Fluorinated calixpyrroles: anion-binding extractants that reduce the Hofmeister bias

Tatiana G. Levitskaia; Manuel Marquez; Jonathan L. Sessler; James A. Shriver; Thomas Vercouter; Bruce A. Moyer

doi:10.1039/b306385m

Fluorinated calixpyrroles: anion-binding extractants that reduce the Hofmeister bias

Tatiana G. Levitskaia, Manuel Marquez, Jonathan L. Sessler, James A. Shriver, Thomas Vercouter, Bruce A. Moyer

Chemical Separations Group

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

β-Octafluoro-meso-octamethylcalix[4]pyrrole (1) and β-decafluoro-meso-decamethylcalix[5]pyrrole (2) were found to extract caesium salts of smaller anions (bromide and chloride for 1 and nitrate for 2) as effectively as that of iodide into nitrobenzene (NB) thereby overcoming the Hofmeister bias normally observed for processes of this type.

Original language	English
Pages (from-to)	2248-2249
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	17
DOIs	https://doi.org/10.1039/b306385m
State	Published - 2003

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abstract = "β-Octafluoro-meso-octamethylcalix[4]pyrrole (1) and β-decafluoro-meso-decamethylcalix[5]pyrrole (2) were found to extract caesium salts of smaller anions (bromide and chloride for 1 and nitrate for 2) as effectively as that of iodide into nitrobenzene (NB) thereby overcoming the Hofmeister bias normally observed for processes of this type.",

author = "Levitskaia, {Tatiana G.} and Manuel Marquez and Sessler, {Jonathan L.} and Shriver, {James A.} and Thomas Vercouter and Moyer, {Bruce A.}",

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T1 - Fluorinated calixpyrroles

T2 - anion-binding extractants that reduce the Hofmeister bias

AU - Levitskaia, Tatiana G.

AU - Marquez, Manuel

AU - Sessler, Jonathan L.

AU - Shriver, James A.

AU - Vercouter, Thomas

AU - Moyer, Bruce A.

PY - 2003

Y1 - 2003

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AB - β-Octafluoro-meso-octamethylcalix[4]pyrrole (1) and β-decafluoro-meso-decamethylcalix[5]pyrrole (2) were found to extract caesium salts of smaller anions (bromide and chloride for 1 and nitrate for 2) as effectively as that of iodide into nitrobenzene (NB) thereby overcoming the Hofmeister bias normally observed for processes of this type.

UR - http://www.scopus.com/inward/record.url?scp=0041733853&partnerID=8YFLogxK

U2 - 10.1039/b306385m

DO - 10.1039/b306385m

M3 - Article

AN - SCOPUS:0041733853

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SP - 2248

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JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Fluorinated calixpyrroles: anion-binding extractants that reduce the Hofmeister bias

Abstract

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