Abstract
The current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition, the powders were prepared by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical conductivity, thermal expansion, and sinterability behaviour. Coated steel samples were oxidised in an air atmosphere at 750 °C for 3000 h. In parallel, a state-of-the-art MnCo2O4 spinel oxide was tested as a reference. The coatings and oxide scale microstructures of the surfaces and cross-sections were examined by XRD, and SEM-EDX. TEM-EDX, XRF, and micro-XRD were also performed on the cross-section lamellae. The electrical properties of the steel-coating system were evaluated by Area Specific Resistance measurement. The results confirm that Mn–Cu–Fe oxides exhibit higher conductivity and lower TEC than Mn–Co oxide. Based on the obtained results, it might be concluded that the proposed coatings are a promising alternative to coatings that contain cobalt.
| Original language | English |
|---|---|
| Pages (from-to) | 36076-36093 |
| Number of pages | 18 |
| Journal | International Journal of Hydrogen Energy |
| Volume | 48 |
| Issue number | 92 |
| DOIs | |
| State | Published - Nov 29 2023 |
| Externally published | Yes |
Funding
This work is supported by National Science Centre Harmonia 9 project number UMO-2017/26/M/ST8/00438: “Quest for novel materials for solid oxide cell interconnect coatings”. The TEM measurement and analysis have been financed by the project from the European Union's Horizon 2020 research and innovation program under grant agreement No 823717 and it was performed by the Chalmers Material Analysis Laboratory, CMAL – ESTEEM3. The authors would like to acknowledge the Paul Scherrer Institute, Villigen, Switzerland for access to beamtime at the microXAS beamline of the Swiss Light Source. This work is supported by National Science Centre Harmonia 9 project number UMO-2017/26/M/ST8/00438 : “Quest for novel materials for solid oxide cell interconnect coatings”. The TEM measurement and analysis have been financed by the project from the European Union’s Horizon 2020 research and innovation program under grant agreement No 823717 and it was performed by the Chalmers Material Analysis Laboratory, CMAL – ESTEEM3. The authors would like to acknowledge the Paul Scherrer Institute, Villigen, Switzerland for access to beamtime at the microXAS beamline of the Swiss Light Source.