Facile synthesis of a linear porous organic polymer: Via Schiff-base chemistry for propyne/propylene separation

Shengtai Hou, Xian Suo, Nanqing Chen, Pengfei Zhang, Sheng Dai

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

Linear porous organic polymers (L-POPs) are a class of porous organic materials that are of great interest in various applications, such as separation and catalysis. However, the limited reaction types and requirement for specific monomers restrict the range of L-POPs possible. Herein, we introduce the facile synthesis of an L-POP via Schiff-base chemistry, and describe an L-POP material with good solubility in organic solvents. The L-POP also exhibited a certain degree selectivity in the separation of propyne/propylene (C3H4/C3H6; very close boiling points and similar kinetic diameters).

Original languageEnglish
Pages (from-to)4382-4386
Number of pages5
JournalPolymer Chemistry
Volume11
Issue number27
DOIs
StatePublished - Jul 21 2020

Funding

This work was supported by the National Natural Science Foundation of China (Grant No. 21776174), Shanghai Rising-Star Program (20QA1405200), the Open Foundation of the State Key Laboratory of Ocean Engineering (Shanghai Jiao Tong University of China) (No. 1809), Shanghai Jiao Tong University Scientific and Technological Innovation Funds (No. 2019QYB06), China Shipbuilding Industry Corporation (CSIC) and Zhejiang XinAn Chemical Industrial Group.

FundersFunder number
China Shipbuilding Industry Corporation
Open Foundation of the State Key Laboratory of Ocean Engineering
Shanghai Jiao Tong University Scientific and Technological Innovation Funds
Shanghai Jiao Tong University of China
Zhejiang Xinan Chemical Industrial Group
National Natural Science Foundation of China21776174
Shanghai Jiao Tong University2019QYB06, 1809
State Key Laboratory of Ocean Engineering
Shanghai Rising-Star Program20QA1405200
China Shipbuilding Industry

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