Facile Fabricating Hierarchically Porous Metal-Organic Frameworks via a Template-Free Strategy

Yu Cao; Yali Ma; Tao Wang; Xue Wang; Qisheng Huo; Yunling Liu

doi:10.1021/acs.cgd.5b01559

Facile Fabricating Hierarchically Porous Metal-Organic Frameworks via a Template-Free Strategy

Yu Cao, Yali Ma, Tao Wang, Xue Wang, Qisheng Huo, Yunling Liu

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Tunable Cu-BTC mesoporous metal-organic frameworks (mesoMOFs) are prepared conveniently through a template-free strategy under solvothermal conditions. Nanosized microporous Cu-BTC particles pack to form mesopores with sizes that can be controlled (26-72 nm) by simply varying the synthesis temperature. This template-free and controllable strategy can be applied using other organic solvents to obtain mesoMOF materials that possess similar tunable mesopores. Furthermore, the as-synthesized hierarchically porous MOFs materials are demonstrated as the electrocatalysts for oxygen reduction reaction under mild conditions.

Original language	English
Pages (from-to)	504-510
Number of pages	7
Journal	Crystal Growth and Design
Volume	16
Issue number	1
DOIs	https://doi.org/10.1021/acs.cgd.5b01559
State	Published - Jan 6 2016
Externally published	Yes

Funding

This work was supported by the National Natural Science Foundation of China (Grant Nos. 21171064, 21371067, and 21373095). The authors would like to thank Jacilynn Brant for helpful discussions.

Funders	Funder number
National Natural Science Foundation of China	21371067, 21171064, 21373095

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abstract = "Tunable Cu-BTC mesoporous metal-organic frameworks (mesoMOFs) are prepared conveniently through a template-free strategy under solvothermal conditions. Nanosized microporous Cu-BTC particles pack to form mesopores with sizes that can be controlled (26-72 nm) by simply varying the synthesis temperature. This template-free and controllable strategy can be applied using other organic solvents to obtain mesoMOF materials that possess similar tunable mesopores. Furthermore, the as-synthesized hierarchically porous MOFs materials are demonstrated as the electrocatalysts for oxygen reduction reaction under mild conditions.",

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AU - Wang, Xue

AU - Huo, Qisheng

AU - Liu, Yunling

PY - 2016/1/6

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N2 - Tunable Cu-BTC mesoporous metal-organic frameworks (mesoMOFs) are prepared conveniently through a template-free strategy under solvothermal conditions. Nanosized microporous Cu-BTC particles pack to form mesopores with sizes that can be controlled (26-72 nm) by simply varying the synthesis temperature. This template-free and controllable strategy can be applied using other organic solvents to obtain mesoMOF materials that possess similar tunable mesopores. Furthermore, the as-synthesized hierarchically porous MOFs materials are demonstrated as the electrocatalysts for oxygen reduction reaction under mild conditions.

AB - Tunable Cu-BTC mesoporous metal-organic frameworks (mesoMOFs) are prepared conveniently through a template-free strategy under solvothermal conditions. Nanosized microporous Cu-BTC particles pack to form mesopores with sizes that can be controlled (26-72 nm) by simply varying the synthesis temperature. This template-free and controllable strategy can be applied using other organic solvents to obtain mesoMOF materials that possess similar tunable mesopores. Furthermore, the as-synthesized hierarchically porous MOFs materials are demonstrated as the electrocatalysts for oxygen reduction reaction under mild conditions.

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Facile Fabricating Hierarchically Porous Metal-Organic Frameworks via a Template-Free Strategy

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