Abstract
A low-cost, nonvacuum, solution precursor route has been developed to produce epitaxial oxide buffer layers of Eu2O3 or La2Zr2O7 on biaxially textured Ni (100) tapes. A reel-to-reel continuous dip-coating unit consisting of a constant-tension tape transport system attached to a controlled atmosphere furnace was fabricated. Nickel tapes were pulled through a 2-methoxyethanol solution of europium methoxyethoxide/acetate or lanthanum zirconium methoxyethoxide. The double-sided dip-coated tapes were then annealed in a preheated furnace at 1000°-1100 °C with a high flow rate of Ar/H2 (4%) gas. The dip-coated buffers were dense, continuous, crack-free, and epitaxial with a single cube texture. A critical current (Jc) of >1 MA/cm2 at 77 K and self-field was obtained for YBa2Cu3O7-δ (YBCO) films with a layer sequence of YBCO (ex situ BaF2 process)/CeO2 (sputtered)/YSZ (sputtered)/Eu2O3 (dip-coated)/nickel. We have produced 1-2 m lengths of epitaxial buffer layers on textured nickel substrates using a nonvacuum process for the first time.
Original language | English |
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Pages (from-to) | 273-278 |
Number of pages | 6 |
Journal | Journal of the American Ceramic Society |
Volume | 84 |
Issue number | 2 |
DOIs | |
State | Published - 2001 |