Fabrication of long lengths of epitaxial buffer layers on biaxially textured nickel substrates using a continuous reel-to-reel dip-coating unit

M. Parans Paranthaman, Thomas G. Chirayil, Fred A. List, Xingtian Cui, Amit Goyal, Dominic F. Lee, Eliot D. Specht, Patrick M. Martin, Robert K. Williams, Donald M. Kroeger, Jonathan S. Morrell, David B. Beach, Ron Feenstra, David K. Christen

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

A low-cost, nonvacuum, solution precursor route has been developed to produce epitaxial oxide buffer layers of Eu2O3 or La2Zr2O7 on biaxially textured Ni (100) tapes. A reel-to-reel continuous dip-coating unit consisting of a constant-tension tape transport system attached to a controlled atmosphere furnace was fabricated. Nickel tapes were pulled through a 2-methoxyethanol solution of europium methoxyethoxide/acetate or lanthanum zirconium methoxyethoxide. The double-sided dip-coated tapes were then annealed in a preheated furnace at 1000°-1100 °C with a high flow rate of Ar/H2 (4%) gas. The dip-coated buffers were dense, continuous, crack-free, and epitaxial with a single cube texture. A critical current (Jc) of >1 MA/cm2 at 77 K and self-field was obtained for YBa2Cu3O7-δ (YBCO) films with a layer sequence of YBCO (ex situ BaF2 process)/CeO2 (sputtered)/YSZ (sputtered)/Eu2O3 (dip-coated)/nickel. We have produced 1-2 m lengths of epitaxial buffer layers on textured nickel substrates using a nonvacuum process for the first time.

Original languageEnglish
Pages (from-to)273-278
Number of pages6
JournalJournal of the American Ceramic Society
Volume84
Issue number2
DOIs
StatePublished - 2001

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