Extraction of trivalent lanthanides and actinides by 'MPO-like' calixarenes

Lætitia H. Delmau; Nicole Simon; Marie José Schwing-Weill; Françoise Arnaud-Neu; Jean François Dozol; Serge Eymard; Bernard Tournois; Cordula Grüttner; Christian Musigmann; Abdi Tunayar; Volker Böhmer

doi:10.1080/01496399908951071

Extraction of trivalent lanthanides and actinides by 'MPO-like' calixarenes

Lætitia H. Delmau
, Nicole Simon
, Marie José Schwing-Weill
, Françoise Arnaud-Neu
, Jean François Dozol
, Serge Eymard
, Bernard Tournois
, Cordula Grüttner
, Christian Musigmann
, Abdi Tunayar
, Volker Böhmer

Process Coordination

Research output: Contribution to journal › Conference article › peer-review

59 Scopus citations

Abstract

Extractive properties of calix[4]arenes bearing carbamoylmethylphosphine oxide moieties on their upper rim toward trivalent lanthanide and actinide cations were investigated. The study revealed that these molecules selectively extract light lanthanides and actinides from heavy lanthanides. All parameters present in the extraction system were varied to determine the origin of the selectivity. It was found that this selectivity requires a calix[4]arene platform and acetamidophosphine oxide groups containing phenyl substituents on the four phosphorus atoms.

Original language	English
Pages (from-to)	863-876
Number of pages	14
Journal	Separation Science and Technology (Philadelphia)
Volume	34
Issue number	6-7
DOIs	https://doi.org/10.1080/01496399908951071
State	Published - 1999
Event	Proceedings of the 1997 10th Symposium on Separation Science and Technology for Energy Applications - Gatlinburg, TN, USA Duration: Oct 20 1997 → Oct 24 1997

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10.1080/01496399908951071

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title = "Extraction of trivalent lanthanides and actinides by 'MPO-like' calixarenes",

abstract = "Extractive properties of calix[4]arenes bearing carbamoylmethylphosphine oxide moieties on their upper rim toward trivalent lanthanide and actinide cations were investigated. The study revealed that these molecules selectively extract light lanthanides and actinides from heavy lanthanides. All parameters present in the extraction system were varied to determine the origin of the selectivity. It was found that this selectivity requires a calix[4]arene platform and acetamidophosphine oxide groups containing phenyl substituents on the four phosphorus atoms.",

author = "Delmau, \{L{\ae}titia H.\} and Nicole Simon and Schwing-Weill, \{Marie Jos{\'e}\} and Fran{\c c}oise Arnaud-Neu and Dozol, \{Jean Fran{\c c}ois\} and Serge Eymard and Bernard Tournois and Cordula Gr{\"u}ttner and Christian Musigmann and Abdi Tunayar and Volker B{\"o}hmer",

year = "1999",

doi = "10.1080/01496399908951071",

language = "English",

volume = "34",

pages = "863--876",

journal = "Separation Science and Technology (Philadelphia)",

issn = "0149-6395",

publisher = "Taylor and Francis Group",

number = "6-7",

note = "Proceedings of the 1997 10th Symposium on Separation Science and Technology for Energy Applications ; Conference date: 20-10-1997 Through 24-10-1997",

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TY - JOUR

T1 - Extraction of trivalent lanthanides and actinides by 'MPO-like' calixarenes

AU - Delmau, Lætitia H.

AU - Simon, Nicole

AU - Schwing-Weill, Marie José

AU - Arnaud-Neu, Françoise

AU - Dozol, Jean François

AU - Eymard, Serge

AU - Tournois, Bernard

AU - Grüttner, Cordula

AU - Musigmann, Christian

AU - Tunayar, Abdi

AU - Böhmer, Volker

PY - 1999

Y1 - 1999

N2 - Extractive properties of calix[4]arenes bearing carbamoylmethylphosphine oxide moieties on their upper rim toward trivalent lanthanide and actinide cations were investigated. The study revealed that these molecules selectively extract light lanthanides and actinides from heavy lanthanides. All parameters present in the extraction system were varied to determine the origin of the selectivity. It was found that this selectivity requires a calix[4]arene platform and acetamidophosphine oxide groups containing phenyl substituents on the four phosphorus atoms.

AB - Extractive properties of calix[4]arenes bearing carbamoylmethylphosphine oxide moieties on their upper rim toward trivalent lanthanide and actinide cations were investigated. The study revealed that these molecules selectively extract light lanthanides and actinides from heavy lanthanides. All parameters present in the extraction system were varied to determine the origin of the selectivity. It was found that this selectivity requires a calix[4]arene platform and acetamidophosphine oxide groups containing phenyl substituents on the four phosphorus atoms.

UR - https://www.scopus.com/pages/publications/0033053764

U2 - 10.1080/01496399908951071

DO - 10.1080/01496399908951071

M3 - Conference article

AN - SCOPUS:0033053764

SN - 0149-6395

VL - 34

SP - 863

EP - 876

JO - Separation Science and Technology (Philadelphia)

JF - Separation Science and Technology (Philadelphia)

IS - 6-7

T2 - Proceedings of the 1997 10th Symposium on Separation Science and Technology for Energy Applications

Y2 - 20 October 1997 through 24 October 1997

ER -

Extraction of trivalent lanthanides and actinides by 'MPO-like' calixarenes

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