Abstract
By use of the modeling program SXLSQA, it has been possible to perform an extensive equilibrium analysis of the extraction of Mn(II) from nitric acid by didoclecylnaphthalene sulfonic acid (HDDNS) in combination with either f-butylbenzo-15-crown-5 (tBB15C5) or f-butyIcyclohexano-15-crown-5 (IBC15C5) in toluene. Overall, only 1:1 metalxrown ether interactions have been found, and HDDNS acts both.
| Original language | English |
|---|---|
| Pages (from-to) | 889-921 |
| Number of pages | 33 |
| Journal | Solvent Extraction and Ion Exchange |
| Volume | 11 |
| Issue number | 5 |
| DOIs | |
| State | Published - Oct 10 1993 |
| Externally published | Yes |
Funding
The submitted manuscript bas been authored by s contractor of the U. S. Government under contract No. DE-AC05-840R21400. Accordingly, the U. S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others (o do so, for U. S. Government purposes. 'This research was funded by the Division of Chemical Sciences, Office of Basic Energy Sciences, US. Department of Energy under contract DE-AC05-840RZ1400 with Martin Marietta Energy Systems, Inc. The participation of ktitia H. Delmau in this research was made possible by a travel grant from the Rectorat de I'Acadhie de Paris. This research was funded by the Division of Chemical Sciences. Office of Basic Energy Sciences, U.S. Department of Energy under contract DE-AC05-840R21400 with Manin Marietta Energy Systems. Inc. The participation of Lletitia H. Delmau in this research was made possible by a travel grant from the Rectorat de I'AcadCmie de Paris. We are grateful both to W. J. McDowell for helpful discussions and for kindly providing access to the extraction data and to C. F. Coleman for helpful comments in preparation of this manuscript.
| Funders | Funder number |
|---|---|
| U. S. Government | DE-AC05-840R21400 |
| U.S. Department of Energy | DE-AC05-840RZ1400 |
| Division of Chemical Sciences | |
| Basic Energy Sciences | |
| Rectorat de I'Acadhie de Paris | |
| U.S. Department of Energy | DE-AC05-840R21400 |
| Rectorat de I'AcadCmie de Paris | |
| Division of Chemical Sciences | |
| Basic Energy Sciences |