Experimental validation of long term thermal exposure sensitization of AA5xxx alloys

Yakun Zhu, Soumya Kar, Michael L. Free, David A. Cullen, Lawrence F. Allard

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Scopus citations

Abstract

In the present work, β-phase formation along grain boundaries has been evaluated by scanning transmission electron microscopy (STEM) and energy-dispersive X-ray spectroscopy (EDS) analysis methods. The thickness of β-phase along grain boundaries, measured by STEM for a 1-year thermally treated sample, was estimated to be 15 - 20 nm. Etching effects of phosphoric acid solution and ammonium persulfate solution on the Al matrix are discussed. The effect of ASTM G67 nitric acid attack on different surfaces was investigated. Mass loss data was collected for several AA5xxx alloys using long-term (∼ 12 months), constant temperature (40 to 70°C) exposure tests. Other samples were treated in thermal exposure furnaces with cyclic temperatures (40 to 45°C and 50 to 70°C) to represent the heating cycles in service conditions.

Original languageEnglish
Title of host publicationNACE - International Corrosion Conference Series
Pages3439-3446
Number of pages8
StatePublished - 2012
EventCorrosion 2012 - Salt Lake City, UT, United States
Duration: Mar 11 2012Mar 15 2012

Publication series

NameNACE - International Corrosion Conference Series
Volume4
ISSN (Print)0361-4409

Conference

ConferenceCorrosion 2012
Country/TerritoryUnited States
CitySalt Lake City, UT
Period03/11/1203/15/12

Keywords

  • ASTM G67
  • EDS
  • STEM
  • Sensitization
  • β-phase

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