Experimental determination of energy-level structures of diamond silicon-vacancy centers in off-axis magnetic fields

Shu Hao Wu, Xinzhu Li, Ian Gallagher, Lexington Mandachi, Benjamin Lawrie, Hailin Wang

Research output: Contribution to journalArticlepeer-review

Abstract

We report the development of an experimental approach to efficiently determine the energy level structure of an individual silicon vacancy (SiV) center in a magnetic field along an arbitrary direction. This approach uses two coupling rates (one each for the ground and the excited states) to characterize the combined effects of static strain and dynamic Jahn-Teller coupling and exploits the fact that orbital Zeeman effects vanish when the magnetic field is normal to the SiV axis. With an analytical expression for the energy level structure of the SiV under a transverse magnetic field, the two coupling rates can be directly derived from two measurements: one on the frequency separation between two spin-conserved transitions and the other on the coherent population trapping resonance of the SiV ground spin states. A detailed comparison between the numerical calculation and the experimental result on the dependence of the spin-conserved splitting on both the amplitude and direction of the magnetic field further reveals unequal orbital magnetic coupling for the ground and excited states, indicating that unequal orbital quenching factors are needed for an accurate description of the SiV energy level structure in a magnetic field.

Original languageEnglish
Article number155426
JournalPhysical Review B
Volume111
Issue number15
DOIs
StatePublished - Apr 15 2025

Funding

The research effort at the University of Oregon has been supported by the NSF under Grants No. 2012524 and No. 2003074. The effort at the Oak Ridge National Laboratory has been supported by the U. S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division.

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