Abstract
Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxidation state +4. The complexes are extremely stable in the crystalline state and in solutions and show rich redox chemistry.
| Original language | English |
|---|---|
| Pages (from-to) | 11060-11063 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 57 |
| Issue number | 84 |
| DOIs | |
| State | Published - Oct 28 2021 |
Funding
The project has received funding from the European Union’s Horizon 2020 Research and Innovation Programme under the Marie Skłodowska-Curie grant agreement no. 778245. AOH and IOF acknowledge funding received from the Ministry of Education and Science of Ukraine (grant no. 19BF037-04). The high-field EPR spectra were recorded at the NHMFL, which is funded by the NSF through the Cooperative Agreement No. DMR-1644779, and the State of Florida. This research used resources of the Oak Ridge Leadership Computing Facility (OLCF), which is a DOE Office of Science User Facility supported under Contract DE-AC05-00OR22725.
| Funders | Funder number |
|---|---|
| State of Florida | |
| National Science Foundation | DMR-1644779 |
| Office of Science | DE-AC05-00OR22725 |
| Horizon 2020 Framework Programme | |
| H2020 Marie Skłodowska-Curie Actions | 778245 |
| Ministry of Education and Science of Ukraine | 19BF037-04 |