Evolution of the dynamic susceptibility of simple glass formers in the strongly supercooled regime

S. Adichtchev, T. Blochowicz, C. Gainaru, V. N. Novikov, E. A. Rössler, C. Tschirwitz

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Abstract

We discuss dielectric and light scattering susceptibility spectra of simple glass formers at temperatures above as well as below the critical temperature of the mode coupling theory (MCT). Close to Tg the systems are characterized by the presence of a pronounced excess wing (type A glass formers). The data are analysed within a phenomenological approach, on the one hand, and within MCT, on the other. Among other work we present a complete interpolation of the dielectric data for glycerol (Lunkenheimer et al 2000 Contemp. Phys. 41 15). The crossover temperature Tx, defined by the emergence of the excess wing upon cooling, is extracted from the phenomenological analysis and found to agree well with the critical temperature Tc, extracted from the MCT analysis at high temperatures. Below Tx the evolution of the susceptibility is characterized by a universal appearance of the excess wing. No difference is observed for the non-fragile system with respect to fragile glass formers provided that the wing parameters are studied as a function of the correlation time τα. Finally, a generalized scaling for the susceptibility minimum is proposed which is a phenomenological extension of that of MCT but now also includes the data below Tc.

Original languageEnglish
Pages (from-to)S835-S847
JournalJournal of Physics Condensed Matter
Volume15
Issue number11
DOIs
StatePublished - Mar 26 2003
Externally publishedYes

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