Evidence for a new two-dimensional C 4H-type polymer based on hydrogenated graphene

Danny Haberer; Cristina E. Giusca; Ying Wang; Hermann Sachdev; Alexander V. Fedorov; Mani Farjam; S. Akbar Jafari; Denis V. Vyalikh; Dmitry Usachov; Xianjie Liu; Uwe Treske; Mandy Grobosch; Oleg Vilkov; Vera K. Adamchuk; Stephan Irle; S. Ravi P. Silva; Martin Knupfer; Bernd Büchner; Alexander Grüneis

doi:10.1002/adma.201102019

Evidence for a new two-dimensional C ₄H-type polymer based on hydrogenated graphene

Danny Haberer
, Cristina E. Giusca
, Ying Wang
, Hermann Sachdev
, Alexander V. Fedorov
, Mani Farjam
, S. Akbar Jafari
, Denis V. Vyalikh
, Dmitry Usachov
, Xianjie Liu
, Uwe Treske
, Mandy Grobosch
, Oleg Vilkov
, Vera K. Adamchuk
, Stephan Irle
, S. Ravi P. Silva
, Martin Knupfer
, Bernd Büchner
, Alexander Grüneis

Research output: Contribution to journal › Article › peer-review

104 Scopus citations

Abstract

A new polymer with C ₄H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed "live" on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows for an accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.

Original language	English
Pages (from-to)	4497-4503
Number of pages	7
Journal	Advanced Materials
Volume	23
Issue number	39
DOIs	https://doi.org/10.1002/adma.201102019
State	Published - Oct 18 2011
Externally published	Yes

Keywords

hydrogenated graphene
hydrogenation
polymeric materials
polymerization

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10.1002/adma.201102019

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Haberer, D., Giusca, C. E., Wang, Y., Sachdev, H., Fedorov, A. V., Farjam, M., Jafari, S. A., Vyalikh, D. V., Usachov, D., Liu, X., Treske, U., Grobosch, M., Vilkov, O., Adamchuk, V. K., Irle, S., Silva, S. R. P., Knupfer, M., Büchner, B., & Grüneis, A. (2011). Evidence for a new two-dimensional C ₄H-type polymer based on hydrogenated graphene. Advanced Materials, 23(39), 4497-4503. https://doi.org/10.1002/adma.201102019

@article{618065eff5c345fd88d43f23b675e4ae,

title = "Evidence for a new two-dimensional C 4H-type polymer based on hydrogenated graphene",

abstract = "A new polymer with C 4H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed {"}live{"} on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows for an accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.",

keywords = "hydrogenated graphene, hydrogenation, polymeric materials, polymerization",

author = "Danny Haberer and Giusca, \{Cristina E.\} and Ying Wang and Hermann Sachdev and Fedorov, \{Alexander V.\} and Mani Farjam and Jafari, \{S. Akbar\} and Vyalikh, \{Denis V.\} and Dmitry Usachov and Xianjie Liu and Uwe Treske and Mandy Grobosch and Oleg Vilkov and Adamchuk, \{Vera K.\} and Stephan Irle and Silva, \{S. Ravi P.\} and Martin Knupfer and Bernd B{\"u}chner and Alexander Gr{\"u}neis",

year = "2011",

month = oct,

day = "18",

doi = "10.1002/adma.201102019",

language = "English",

volume = "23",

pages = "4497--4503",

journal = "Advanced Materials",

issn = "0935-9648",

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Haberer, D, Giusca, CE, Wang, Y, Sachdev, H, Fedorov, AV, Farjam, M, Jafari, SA, Vyalikh, DV, Usachov, D, Liu, X, Treske, U, Grobosch, M, Vilkov, O, Adamchuk, VK, Irle, S, Silva, SRP, Knupfer, M, Büchner, B & Grüneis, A 2011, 'Evidence for a new two-dimensional C ₄H-type polymer based on hydrogenated graphene', Advanced Materials, vol. 23, no. 39, pp. 4497-4503. https://doi.org/10.1002/adma.201102019

TY - JOUR

T1 - Evidence for a new two-dimensional C 4H-type polymer based on hydrogenated graphene

AU - Haberer, Danny

AU - Giusca, Cristina E.

AU - Wang, Ying

AU - Sachdev, Hermann

AU - Fedorov, Alexander V.

AU - Farjam, Mani

AU - Jafari, S. Akbar

AU - Vyalikh, Denis V.

AU - Usachov, Dmitry

AU - Liu, Xianjie

AU - Treske, Uwe

AU - Grobosch, Mandy

AU - Vilkov, Oleg

AU - Adamchuk, Vera K.

AU - Irle, Stephan

AU - Silva, S. Ravi P.

AU - Knupfer, Martin

AU - Büchner, Bernd

AU - Grüneis, Alexander

PY - 2011/10/18

Y1 - 2011/10/18

N2 - A new polymer with C 4H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed "live" on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows for an accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.

AB - A new polymer with C 4H stoichiometry based on graphene is synthesized in situ using template-induced polymerization of self-organizing hydrogen adsorbates on graphene. The polymerization is observed "live" on the surface of graphene by photoemission spectroscopy. Photoemission spectroscopy allows for an accurate determination of the carbon/hydrogen stoichiometry, an aspect that is extremely important for understanding functionalized graphene.

KW - hydrogenated graphene

KW - hydrogenation

KW - polymeric materials

KW - polymerization

UR - https://www.scopus.com/pages/publications/80054711000

U2 - 10.1002/adma.201102019

DO - 10.1002/adma.201102019

M3 - Article

C2 - 21997302

AN - SCOPUS:80054711000

SN - 0935-9648

VL - 23

SP - 4497

EP - 4503

JO - Advanced Materials

JF - Advanced Materials

IS - 39

ER -

Evidence for a new two-dimensional C ₄H-type polymer based on hydrogenated graphene

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Keywords

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