Establishing substitution rules of functional groups for high-capacity organic anode materials in Na-ion batteries

Kathryn Holguin, Kaiqiang Qin, Ethan Phillip Kamphaus, Fu Chen, Lei Cheng, Gui Liang Xu, Khalil Amine, Chao Luo

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Tailoring molecular structures of organic electrode materials (OEMs) can enhance their performance in Na-ion batteries, however, the substitution rules and the consequent effect on the specific capacity and working potential remain elusive. Herein, by examining three sodium carboxylates with selective N substitution or extended conjugation structure, we exploited the correlation between structure and performance to establish substitution rules for high-capacity OEMs. Our results show that substitution position and types of functional groups are essential to create active centers for uptake/removal of Na+ and thermodynamically stabilize organic structures. Furthermore, rational host design and electrolytes modulation were performed to extend the cycle life to 500 cycles. A full cell based on the optimal 2,2′-bipyridine-4,4′-dicarboxylic acid disodium salt anode and the polyaniline cathode is demonstrated to confirm the feasibility of achieving all-organic batteries. This work provides a valuable guideline for the design principle of high-capacity and stable OEMs for sustainable energy storage.

Original languageEnglish
Article number231383
JournalJournal of Power Sources
Volume533
DOIs
StatePublished - Jun 15 2022
Externally publishedYes

Keywords

  • Anode
  • Na-ion batteries
  • Organic electrode materials
  • Sodium carboxylate
  • Substitution rules

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