E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH=NH2

Sheng Dai; Qing Xiang Guo; Jih Tzong Wang; Ffrancon Williams

doi:10.1039/C39880001069

E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH₂CH₂CH=NH₂

Sheng Dai
, Qing Xiang Guo
, Jih Tzong Wang
, Ffrancon Williams

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.

Original language	English
Pages (from-to)	1069-1071
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39880001069
State	Published - 1988
Externally published	Yes

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10.1039/C39880001069

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@article{f42a17037cb64d1385668c023cfca316,

title = "E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH=NH2",

abstract = "The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.",

author = "Sheng Dai and Guo, \{Qing Xiang\} and Wang, \{Jih Tzong\} and Ffrancon Williams",

year = "1988",

doi = "10.1039/C39880001069",

language = "English",

pages = "1069--1071",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "16",

}

TY - JOUR

T1 - E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH=NH2

AU - Dai, Sheng

AU - Guo, Qing Xiang

AU - Wang, Jih Tzong

AU - Williams, Ffrancon

PY - 1988

Y1 - 1988

N2 - The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.

AB - The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.

UR - https://www.scopus.com/pages/publications/37049080802

U2 - 10.1039/C39880001069

DO - 10.1039/C39880001069

M3 - Article

AN - SCOPUS:37049080802

SN - 0022-4936

SP - 1069

EP - 1071

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH₂CH₂CH=NH₂

Abstract

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