Equimolar CO 2 capture by N-substituted amino acid salts and subsequent conversion

An Hua Liu; Ran Ma; Chan Song; Zhen Zhen Yang; Ao Yu; Yu Cai; Liang Nian He; Ya Nan Zhao; Bing Yu; Qing Wen Song

doi:10.1002/anie.201205362

Equimolar CO ₂ capture by N-substituted amino acid salts and subsequent conversion

An Hua Liu, Ran Ma, Chan Song, Zhen Zhen Yang, Ao Yu, Yu Cai, Liang Nian He, Ya Nan Zhao, Bing Yu, Qing Wen Song

Research output: Contribution to journal › Article › peer-review

220 Scopus citations

Abstract

Steric bulk controls CO ₂ absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO ₂ in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO ₂; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO ₂ could be converted directly into oxazolidinones and thus CO ₂ desorption could be sidestepped.

Original language	English
Pages (from-to)	11306-11310
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	45
DOIs	https://doi.org/10.1002/anie.201205362
State	Published - Nov 5 2012
Externally published	Yes

Keywords

amino acids
carbamic acid
carbon dioxide fixation
catalysis
poly(ethylene glycol)

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/anie.201205362

Cite this

@article{e662d95f95d944009e007372d3daaf04,

title = "Equimolar CO 2 capture by N-substituted amino acid salts and subsequent conversion",

abstract = "Steric bulk controls CO 2 absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO 2 in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO 2; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO 2 could be converted directly into oxazolidinones and thus CO 2 desorption could be sidestepped.",

keywords = "amino acids, carbamic acid, carbon dioxide fixation, catalysis, poly(ethylene glycol)",

author = "Liu, {An Hua} and Ran Ma and Chan Song and Yang, {Zhen Zhen} and Ao Yu and Yu Cai and He, {Liang Nian} and Zhao, {Ya Nan} and Bing Yu and Song, {Qing Wen}",

year = "2012",

month = nov,

day = "5",

doi = "10.1002/anie.201205362",

language = "English",

volume = "51",

pages = "11306--11310",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "wiley",

number = "45",

}

TY - JOUR

T1 - Equimolar CO 2 capture by N-substituted amino acid salts and subsequent conversion

AU - Liu, An Hua

AU - Ma, Ran

AU - Song, Chan

AU - Yang, Zhen Zhen

AU - Yu, Ao

AU - Cai, Yu

AU - He, Liang Nian

AU - Zhao, Ya Nan

AU - Yu, Bing

AU - Song, Qing Wen

PY - 2012/11/5

Y1 - 2012/11/5

N2 - Steric bulk controls CO 2 absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO 2 in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO 2; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO 2 could be converted directly into oxazolidinones and thus CO 2 desorption could be sidestepped.

AB - Steric bulk controls CO 2 absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO 2 in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO 2; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO 2 could be converted directly into oxazolidinones and thus CO 2 desorption could be sidestepped.

KW - amino acids

KW - carbamic acid

KW - carbon dioxide fixation

KW - catalysis

KW - poly(ethylene glycol)

UR - http://www.scopus.com/inward/record.url?scp=84868143897&partnerID=8YFLogxK

U2 - 10.1002/anie.201205362

DO - 10.1002/anie.201205362

M3 - Article

C2 - 23042720

AN - SCOPUS:84868143897

SN - 1433-7851

VL - 51

SP - 11306

EP - 11310

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 45

ER -