Abstract
Interplay between charge density wave (CDW) order and superconductivity (SC) in quasi-two-dimensional materials remains poorly understood due to their diverse experimental varieties. Here, we investigate the pressure-dependent electrical transport and Raman scattering spectra of 2H-Pd0.05TaSe2, which exhibits a CDW transition at TCDW = 115 K and a superconducting transition at Tc = 2.6 K at ambient pressure conditions. As pressure increases, TCDW, identified by the resistivity anomaly, shifts towards lower temperatures and approaches zero at a critical pressure of Pc ~ 21.5 GPa. At this critical pressure, both Tc and upper critical field Hc2 reach their maximum values of ~ 8.5 K and ~ 6.4 T, respectively. Analysis of the Raman scattering spectra demonstrates that increasing pressure systematically suppresses both the two-phonon spectral weight above TCDW and the CDW amplitudon energies below TCDW, leading to their simultaneous disappearance at Pc. These observations provide direct evidence for the formation of a CDW quantum critical point (QCP) at Pc, indicating that charge and lattice fluctuations associated with the QCP of strongly coupled CDW order may enhance SC in pressurized 2H-Pd0.05TaSe2.
| Original language | English |
|---|---|
| Article number | 8 |
| Journal | NPG Asia Materials |
| Volume | 17 |
| Issue number | 1 |
| DOIs | |
| State | Published - Dec 2025 |
| Externally published | Yes |
Funding
Y. S., D. H. G., and K. H. K. were financially supported by the Ministry of Science and ICT through the National Research Foundation of Korea (2022H1D3A3A01077468, 2019R1A2C2090648) and by the Ministry of Education (2021R1A6C101B418). We appreciate Duck Young Kim for valuable discussions. (2021R1A6C101B418).