Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]

J. Palmer West; Dino Sulejmanovic; Gregory Becht; Jian He; Dale Hitchcock; Yonggao Yan; Shiou Jyh Hwu

doi:10.1016/j.jssc.2013.07.033

Enhanced ferromagnetic order in Sr₄Mn₃O ₃(GeO₄)₃ featuring canted [MnO₄]

J. Palmer West
, Dino Sulejmanovic
, Gregory Becht
, Jian He
, Dale Hitchcock
, Yonggao Yan
, Shiou Jyh Hwu

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Crystals of Sr_4-xLn_xMn₃O ₃(GeO₄)₃ (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na₃LnMn₃O₃(AsO ₄)₃ (Ln=La, Sm, Gd) series that contains the same [MnO₄].

Original language	English
Pages (from-to)	51-59
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	206
DOIs	https://doi.org/10.1016/j.jssc.2013.07.033
State	Published - 2013
Externally published	Yes

Funding

Financial support for this research ( DMR-0322905 , 0706426 ) from the National Science Foundation (NSF) is gratefully acknowledged.

Keywords

Chain structures
Double aliovalent substitution
Ferromagnetism
Kagomé
Mixed-valent compounds

Access to Document

10.1016/j.jssc.2013.07.033

Cite this

@article{e6f6351cd05f49de80b5be7b7f98f20d,

title = "Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]",

abstract = "Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x\textasciitilde{}0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x\textasciitilde{}0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].",

keywords = "Chain structures, Double aliovalent substitution, Ferromagnetism, Kagom{\'e}, Mixed-valent compounds",

author = "West, \{J. Palmer\} and Dino Sulejmanovic and Gregory Becht and Jian He and Dale Hitchcock and Yonggao Yan and Hwu, \{Shiou Jyh\}",

year = "2013",

doi = "10.1016/j.jssc.2013.07.033",

language = "English",

volume = "206",

pages = "51--59",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Elsevier",

}

TY - JOUR

T1 - Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]

AU - West, J. Palmer

AU - Sulejmanovic, Dino

AU - Becht, Gregory

AU - He, Jian

AU - Hitchcock, Dale

AU - Yan, Yonggao

AU - Hwu, Shiou Jyh

PY - 2013

Y1 - 2013

N2 - Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].

AB - Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].

KW - Chain structures

KW - Double aliovalent substitution

KW - Ferromagnetism

KW - Kagomé

KW - Mixed-valent compounds

UR - https://www.scopus.com/pages/publications/84881512207

U2 - 10.1016/j.jssc.2013.07.033

DO - 10.1016/j.jssc.2013.07.033

M3 - Article

AN - SCOPUS:84881512207

SN - 0022-4596

VL - 206

SP - 51

EP - 59

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -