Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]

J. Palmer West; Dino Sulejmanovic; Gregory Becht; Jian He; Dale Hitchcock; Yonggao Yan; Shiou Jyh Hwu

doi:10.1016/j.jssc.2013.07.033

Enhanced ferromagnetic order in Sr₄Mn₃O ₃(GeO₄)₃ featuring canted [MnO₄]

J. Palmer West, Dino Sulejmanovic, Gregory Becht, Jian He, Dale Hitchcock, Yonggao Yan, Shiou Jyh Hwu

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Crystals of Sr_4-xLn_xMn₃O ₃(GeO₄)₃ (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na₃LnMn₃O₃(AsO ₄)₃ (Ln=La, Sm, Gd) series that contains the same [MnO₄].

Original language	English
Pages (from-to)	51-59
Number of pages	9
Journal	Journal of Solid State Chemistry
Volume	206
DOIs	https://doi.org/10.1016/j.jssc.2013.07.033
State	Published - 2013
Externally published	Yes

Funding

Financial support for this research ( DMR-0322905 , 0706426 ) from the National Science Foundation (NSF) is gratefully acknowledged.

Funders	Funder number
National Science Foundation
Directorate for Mathematical and Physical Sciences	0706426

Keywords

Chain structures
Double aliovalent substitution
Ferromagnetism
Kagomé
Mixed-valent compounds

Access to Document

10.1016/j.jssc.2013.07.033

Cite this

@article{e6f6351cd05f49de80b5be7b7f98f20d,

title = "Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]",

abstract = "Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].",

keywords = "Chain structures, Double aliovalent substitution, Ferromagnetism, Kagom{\'e}, Mixed-valent compounds",

author = "West, {J. Palmer} and Dino Sulejmanovic and Gregory Becht and Jian He and Dale Hitchcock and Yonggao Yan and Hwu, {Shiou Jyh}",

year = "2013",

doi = "10.1016/j.jssc.2013.07.033",

language = "English",

volume = "206",

pages = "51--59",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Elsevier",

}

TY - JOUR

T1 - Enhanced ferromagnetic order in Sr4Mn3O 3(GeO4)3 featuring canted [MnO4]

AU - West, J. Palmer

AU - Sulejmanovic, Dino

AU - Becht, Gregory

AU - He, Jian

AU - Hitchcock, Dale

AU - Yan, Yonggao

AU - Hwu, Shiou Jyh

PY - 2013

Y1 - 2013

N2 - Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].

AB - Crystals of Sr4-xLnxMn3O 3(GeO4)3 (x=0; x~0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x~0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na3LnMn3O3(AsO 4)3 (Ln=La, Sm, Gd) series that contains the same [MnO4].

KW - Chain structures

KW - Double aliovalent substitution

KW - Ferromagnetism

KW - Kagomé

KW - Mixed-valent compounds

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U2 - 10.1016/j.jssc.2013.07.033

DO - 10.1016/j.jssc.2013.07.033

M3 - Article

AN - SCOPUS:84881512207

SN - 0022-4596

VL - 206

SP - 51

EP - 59

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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