Engineering nanoporous organic frameworks to stabilize naked Au clusters: A charge modulation approach

Shunmin Ding; Chengcheng Tian; Xiang Zhu; Huize Wang; Hai Wang; Carter W. Abney; Ning Zhang; Sheng Dai

doi:10.1039/c8cc02966k

Engineering nanoporous organic frameworks to stabilize naked Au clusters: A charge modulation approach

Shunmin Ding, Chengcheng Tian, Xiang Zhu, Huize Wang, Hai Wang, Carter W. Abney, Ning Zhang, Sheng Dai

Chemical Sciences Division

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19 Scopus citations

Abstract

A simple charge modulation approach has been developed to stabilize naked Au clusters on a nanoporous conjugated organic network. Through engineering pore walls with regulated charges, the controllable growth of Au nanoclusters has been realized. The resulting supported catalyst exhibits excellent performance in the aerobic oxidation of alcohols.

Original language	English
Pages (from-to)	5058-5061
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	40
DOIs	https://doi.org/10.1039/c8cc02966k
State	Published - 2018

Bibliographical note

Publisher Copyright:
© 2018 The Royal Society of Chemistry.

Funding

This research was supported financially by the Division of Chemical Science, Geoscience, and Bioscience, Office of Basic Energy Sciences, US Department of Energy. S. Ding, H. Wang, and N. Zhang thank the National Natural Science Foundation of China (No. 21062013) and the Natural Science Foundation of Jiangxi Province (No. 2011ZBAB203013).

Funders	Funder number
Division of Chemical Science
Division of Chemical Science, Geoscience, and Bioscience
Office of Basic Energy Sciences
US Department of Energy
National Natural Science Foundation of China	21062013
Natural Science Foundation of Jiangxi Province	2011ZBAB203013

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title = "Engineering nanoporous organic frameworks to stabilize naked Au clusters: A charge modulation approach",

abstract = "A simple charge modulation approach has been developed to stabilize naked Au clusters on a nanoporous conjugated organic network. Through engineering pore walls with regulated charges, the controllable growth of Au nanoclusters has been realized. The resulting supported catalyst exhibits excellent performance in the aerobic oxidation of alcohols.",

author = "Shunmin Ding and Chengcheng Tian and Xiang Zhu and Huize Wang and Hai Wang and Abney, {Carter W.} and Ning Zhang and Sheng Dai",

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AU - Ding, Shunmin

AU - Tian, Chengcheng

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AU - Wang, Huize

AU - Wang, Hai

AU - Abney, Carter W.

AU - Zhang, Ning

AU - Dai, Sheng

PY - 2018

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AB - A simple charge modulation approach has been developed to stabilize naked Au clusters on a nanoporous conjugated organic network. Through engineering pore walls with regulated charges, the controllable growth of Au nanoclusters has been realized. The resulting supported catalyst exhibits excellent performance in the aerobic oxidation of alcohols.

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JO - Chemical Communications

JF - Chemical Communications

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Engineering nanoporous organic frameworks to stabilize naked Au clusters: A charge modulation approach

Abstract

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