TY - JOUR
T1 - Enabling Informed Decisions on Pyrolysis
T2 - A Key to Turn the Tide on Plastics Recycling
AU - Stathatou, Patritsia Maria
AU - Anglou, Elisavet
AU - Chang, Yuchen
AU - Sweet, Jacob
AU - Ganesan, Arvind
AU - Yutthasaksunthorn, Natechanok
AU - Phillips, Erin V.
AU - Ragam, Nikhita S.
AU - Asensio, Omar Isaac
AU - Nair, Sankar
AU - Boukouvala, Fani
AU - Sievers, Carsten
N1 - Publisher Copyright:
© 2025 The Authors. Published by American Chemical Society.
PY - 2025/6/16
Y1 - 2025/6/16
N2 - The rapid expansion of the plastic industry has led to significant environmental challenges, prompting the exploration of alternative recycling methods. While mechanical recycling has limitations, chemical recycling, particularly pyrolysis, presents a promising solution. However, it faces contention regarding its environmental impacts and economic feasibility. In this perspective, we analyze both supporting and opposing viewpoints of plastic pyrolysis, highlighting the need for transparent, comprehensive, and measurement-informed life cycle assessments (LCAs) of pyrolysis systems to inform decisions. We also present a case study of literature-reported greenhouse gas (GHG) emissions from pyrolysis-derived ultralow sulfur diesel (ULSD) in the United States, showing that depending on plant capacity and co-product allocation methods, emissions can range from 28% lower to 30% higher than fossil-derived ULSD. Similarly, when viewed as a waste management strategy, net GHG emissions from plastic pyrolysis can range from 220% lower to 60% higher than those from current U.S. plastic waste management practices, depending on system conditions. These findings underscore the variability of results and the need for currently missing, robust, and contextualized LCAs. Finally, we discuss regulatory and social challenges and opportunities for the wider adoption of chemical recycling, emphasizing the critical role of public support in realizing the potential of pyrolysis for a circular economy.
AB - The rapid expansion of the plastic industry has led to significant environmental challenges, prompting the exploration of alternative recycling methods. While mechanical recycling has limitations, chemical recycling, particularly pyrolysis, presents a promising solution. However, it faces contention regarding its environmental impacts and economic feasibility. In this perspective, we analyze both supporting and opposing viewpoints of plastic pyrolysis, highlighting the need for transparent, comprehensive, and measurement-informed life cycle assessments (LCAs) of pyrolysis systems to inform decisions. We also present a case study of literature-reported greenhouse gas (GHG) emissions from pyrolysis-derived ultralow sulfur diesel (ULSD) in the United States, showing that depending on plant capacity and co-product allocation methods, emissions can range from 28% lower to 30% higher than fossil-derived ULSD. Similarly, when viewed as a waste management strategy, net GHG emissions from plastic pyrolysis can range from 220% lower to 60% higher than those from current U.S. plastic waste management practices, depending on system conditions. These findings underscore the variability of results and the need for currently missing, robust, and contextualized LCAs. Finally, we discuss regulatory and social challenges and opportunities for the wider adoption of chemical recycling, emphasizing the critical role of public support in realizing the potential of pyrolysis for a circular economy.
KW - chemical recycling
KW - circularity
KW - life cycle assessment
KW - plastic waste
KW - public support
KW - pyrolysis
KW - stakeholder engagement
UR - https://www.scopus.com/pages/publications/105007329889
U2 - 10.1021/acssuschemeng.4c09908
DO - 10.1021/acssuschemeng.4c09908
M3 - Review article
AN - SCOPUS:105007329889
SN - 2168-0485
VL - 13
SP - 8496
EP - 8507
JO - ACS Sustainable Chemistry and Engineering
JF - ACS Sustainable Chemistry and Engineering
IS - 23
ER -