Electrosynthesis and microstructural characterization of anodic Vox films

J. P. Schreckenbach; D. Butte; G. Marx; B. R. Johnson; W. M. Kriven

doi:10.1557/JMR.2000.0213

Electrosynthesis and microstructural characterization of anodic Vo_x films

J. P. Schreckenbach
, D. Butte
, G. Marx
, B. R. Johnson
, W. M. Kriven

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Anodic conversion films of vanadium oxides on vanadium were potentiodynamically generated at high voltages in an acetate electrolyte system. The microstructure of the anodic VO_x coatings was characterized by surface and solid-state techniques such as scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy. An amorphous structure is proposed in which network-forming [VO₄] tetrahedra in various degrees of condensation are connected by distorted [VO₅] and [VO₆] units. Such polyhedra lead to the formation of nanocrystalline phases of stoichiometric and substoichiometric vanadium oxides, which were observed in the amorphous phase.

Original language	English
Pages (from-to)	1483-1489
Number of pages	7
Journal	Journal of Materials Research
Volume	15
Issue number	7
DOIs	https://doi.org/10.1557/JMR.2000.0213
State	Published - Jul 2000
Externally published	Yes

Funding

This work was supported by the Deutsche For-schungsgemeinschaft (DFG) of Germany. Thanks are due to Dr. K. Witke for help with Raman spectroscopy. The work of B.R.J. and W.M.K. in the United States was supported by the United States Air Force Office of Scientific Research (AFOSR) under AASERT Grant No. F49620-97-1-0427.

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title = "Electrosynthesis and microstructural characterization of anodic Vox films",

abstract = "Anodic conversion films of vanadium oxides on vanadium were potentiodynamically generated at high voltages in an acetate electrolyte system. The microstructure of the anodic VOx coatings was characterized by surface and solid-state techniques such as scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy. An amorphous structure is proposed in which network-forming [VO4] tetrahedra in various degrees of condensation are connected by distorted [VO5] and [VO6] units. Such polyhedra lead to the formation of nanocrystalline phases of stoichiometric and substoichiometric vanadium oxides, which were observed in the amorphous phase.",

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year = "2000",

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T1 - Electrosynthesis and microstructural characterization of anodic Vox films

AU - Schreckenbach, J. P.

AU - Butte, D.

AU - Marx, G.

AU - Johnson, B. R.

AU - Kriven, W. M.

PY - 2000/7

Y1 - 2000/7

N2 - Anodic conversion films of vanadium oxides on vanadium were potentiodynamically generated at high voltages in an acetate electrolyte system. The microstructure of the anodic VOx coatings was characterized by surface and solid-state techniques such as scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy. An amorphous structure is proposed in which network-forming [VO4] tetrahedra in various degrees of condensation are connected by distorted [VO5] and [VO6] units. Such polyhedra lead to the formation of nanocrystalline phases of stoichiometric and substoichiometric vanadium oxides, which were observed in the amorphous phase.

AB - Anodic conversion films of vanadium oxides on vanadium were potentiodynamically generated at high voltages in an acetate electrolyte system. The microstructure of the anodic VOx coatings was characterized by surface and solid-state techniques such as scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy. An amorphous structure is proposed in which network-forming [VO4] tetrahedra in various degrees of condensation are connected by distorted [VO5] and [VO6] units. Such polyhedra lead to the formation of nanocrystalline phases of stoichiometric and substoichiometric vanadium oxides, which were observed in the amorphous phase.

UR - https://www.scopus.com/pages/publications/0034236076

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DO - 10.1557/JMR.2000.0213

M3 - Article

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VL - 15

SP - 1483

EP - 1489

JO - Journal of Materials Research

JF - Journal of Materials Research

IS - 7

ER -

Electrosynthesis and microstructural characterization of anodic Vo_x films

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