Electroprecipitation Mechanism Enabling Silica and Hardness Removal through Aluminum-Based Electrocoagulation

Yu Hsuan Liu, Yousuf Z. Bootwala, Gyoung Gug Jang, Jong K. Keum, Chia Miang Khor, Eric M.V. Hoek, David Jassby, Costas Tsouris, Jim Mothersbaugh, Marta C. Hatzell

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

We evaluate the effectiveness of an aluminum-based electrocoagulation pretreatment system to remove dissolved silica and hardness. Silica and hardness limit water recovery during membrane-based desalination applications when silica and hardness exceed the solubility limit and generate scale on the membrane surface. We show that simultaneous removal of nearly all silica (95 ± 4%) and a significant amount of hardness (40-60%) occurs with a hydraulic residence time of 2 h and a charge loading between 0 and 1200 C/L. Increasing the residence time maximized the hardness removal (58 ± 8%) via the formation of larger flocs, which allowed for more constituent removal by gravity settling. We highlight the trade-offs between improved energy efficiency at lower charge loadings and an improved removal rate at a higher charge loading. We further compare the percente of silica and hardness removed in multicomponent solutions and compare this to single component feed solution. We discuss the implications that operational considerations have in terms of cost and treatment capacity. Finally, a cost-benefit analysis comparing chemical coagulation with electrocoagulation indicates that electrocoagulation could be half the cost of chemical coagulation and could produce more stable effluent pH and conductivity.

Original languageEnglish
Pages (from-to)1200-1210
Number of pages11
JournalACS ES and T Engineering
Volume2
Issue number7
DOIs
StatePublished - Jul 8 2022

Funding

This work was supported by the National Alliance for Water Innovation (NAWI), through funding from the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy Office, Advanced Manufacturing Office under Funding Opportunity Announcement DE-FOA-0001905. The authors are also thankful to Yarom Polsky of the Oak Ridge National Laboratory for valuable comments and constructive criticism.

Keywords

  • Electrochemical water treatment
  • aluminum electrocoagulation
  • charge loading
  • hardness
  • silica

Fingerprint

Dive into the research topics of 'Electroprecipitation Mechanism Enabling Silica and Hardness Removal through Aluminum-Based Electrocoagulation'. Together they form a unique fingerprint.

Cite this