Electronic conductivity in Berlin green and Prussian blue

Daniel M. Pajerowski; Takeshi Watanabe; Takashi Yamamoto; Yasuaki Einaga

doi:10.1103/PhysRevB.83.153202

Electronic conductivity in Berlin green and Prussian blue

Daniel M. Pajerowski, Takeshi Watanabe, Takashi Yamamoto, Yasuaki Einaga

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59 Scopus citations

Abstract

We report the temperature dependent (100-300 K) conductivity of Berlin green and Prussian blue powders. The method of electronic conduction in vacuum dried Berlin green is identified as hopping of localized electrons and vacuum dried Prussian blue is reaffirmed as an insulator. The assignment of the conduction mechanism is based upon fits to the experimental data, and the different conductivities of the two samples can be understood in terms of both molecular and simple crystalline energy levels of the solids.

Original language	English
Article number	153202
Journal	Physical Review B - Condensed Matter and Materials Physics
Volume	83
Issue number	15
DOIs	https://doi.org/10.1103/PhysRevB.83.153202
State	Published - Apr 18 2011
Externally published	Yes

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title = "Electronic conductivity in Berlin green and Prussian blue",

abstract = "We report the temperature dependent (100-300 K) conductivity of Berlin green and Prussian blue powders. The method of electronic conduction in vacuum dried Berlin green is identified as hopping of localized electrons and vacuum dried Prussian blue is reaffirmed as an insulator. The assignment of the conduction mechanism is based upon fits to the experimental data, and the different conductivities of the two samples can be understood in terms of both molecular and simple crystalline energy levels of the solids.",

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AB - We report the temperature dependent (100-300 K) conductivity of Berlin green and Prussian blue powders. The method of electronic conduction in vacuum dried Berlin green is identified as hopping of localized electrons and vacuum dried Prussian blue is reaffirmed as an insulator. The assignment of the conduction mechanism is based upon fits to the experimental data, and the different conductivities of the two samples can be understood in terms of both molecular and simple crystalline energy levels of the solids.

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Electronic conductivity in Berlin green and Prussian blue

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