Electronic characterization of silicon intercalated chevron graphene nanoribbons on Au(111)

O. Deniz, C. Sánchez-Sánchez, R. Jaafar, N. Kharche, L. Liang, V. Meunier, X. Feng, K. Müllen, R. Fasel, P. Ruffieux

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Electronic and thermal properties of chevron-type graphene nanoribbons can be widely tuned, making them interesting candidates for electronic and thermoelectric applications. Here, we use post-growth silicon intercalation to unambiguously access nanoribbons' energy position of their electronic frontier states. These are otherwise obscured by substrate effects when investigated directly on the growth substrate. In agreement with first-principles calculations we find a band gap of 2.4 eV.

Original languageEnglish
Pages (from-to)1619-1622
Number of pages4
JournalChemical Communications
Volume54
Issue number13
DOIs
StatePublished - 2018

Funding

This work has been supported by the Swiss National Science Foundation, the Office of Naval Research BRC program (award N00014-12-1-1009), and the European Commission Graphene Flagship (No. CNECT-ICT-604391). CSS is grateful to Ministerio de Economía y Competitividad for financial support via the Juan de la Cierva Incorporación grant (IJCI-2014-19291, co-funded by the European Investment Bank). LL was supported by Eugene Wigner Fellowship at Oak Ridge National Laboratory.

FundersFunder number
Juan de la Cierva IncorporaciónIJCI-2014-19291
Office of Naval Research BRCN00014-12-1-1009
Oak Ridge National Laboratory
Horizon 2020 Framework Programme696656
European CommissionCNECT-ICT-604391
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Ministerio de Economía y Competitividad
European Investment Bank

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