TY - GEN
T1 - Electrode Potentials of Gallium in Fused Alkali Chlorides
AU - Tokarev, Oleg V.
AU - Volkovich, Vladimir A.
AU - Ryzhov, Alexander A.
AU - Maltsev, Dmitry S.
N1 - Publisher Copyright:
© 2022 ECS - The Electrochemical Society.
PY - 2022
Y1 - 2022
N2 - Electrochemical properties of gallium were investigated in 3LiCl-2KCl and 6NaCl-9KCl-5CsCl eutectic based melts at 430-700 and 500-760 °C, respectively. Zero current potentiometry was employed for studying the electrochemical behavior of gallium. Gallium ions in two oxidation states, Ga(III) and Ga(I), were present in the melt in contact with the metal. Formal standard electrode and red-ox potentials of gallium, E∗(Ga/Ga(III), E∗Ga/Ga(I) and E∗Ga(I)/Ga(III), in these molten alkali chloride mixtures were determined.
AB - Electrochemical properties of gallium were investigated in 3LiCl-2KCl and 6NaCl-9KCl-5CsCl eutectic based melts at 430-700 and 500-760 °C, respectively. Zero current potentiometry was employed for studying the electrochemical behavior of gallium. Gallium ions in two oxidation states, Ga(III) and Ga(I), were present in the melt in contact with the metal. Formal standard electrode and red-ox potentials of gallium, E∗(Ga/Ga(III), E∗Ga/Ga(I) and E∗Ga(I)/Ga(III), in these molten alkali chloride mixtures were determined.
UR - http://www.scopus.com/inward/record.url?scp=85140226295&partnerID=8YFLogxK
U2 - 10.1149/10914.0197ecst
DO - 10.1149/10914.0197ecst
M3 - Conference contribution
AN - SCOPUS:85140226295
T3 - ECS Transactions
SP - 197
EP - 204
BT - ECS Transactions
PB - Institute of Physics
T2 - 242nd ECS Meeting
Y2 - 9 October 2022 through 13 October 2022
ER -