Abstract
High-capacity Li[Li0.2Mn0.54Ni0.13 Co 0.13]O2has been successfully synthesized as a cathode material for Liion battery by hydrothermal method. The prepared materials are characterized by XRD, SEM, TEM, EDS, XPS and electrochemical measurements. The XRD result shows that Li[Li0.2Mn0.54Ni 0.13Co0.13]O2material formed a pure phase. SEM and TEM images present a uniformly distributed nanosize of 20-200 nm. The results of CV, charge-discharge tests indicate that this material possesses high discharge capacity and quite good cycling stability. It delivers 251.9 mAhg-1 and 107.5 mAhg-1 for the first cycle and remains 139.4mAhg-1 and 82.7mAhg-1 after 500 cycles, respectively, corresponding to 1 C and 10C.
Original language | English |
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Pages (from-to) | 549-554 |
Number of pages | 6 |
Journal | Electrochimica Acta |
Volume | 107 |
DOIs | |
State | Published - 2013 |
Externally published | Yes |
Funding
This work was supported by the National Basic Research Program of China (973 Program) ( 2013CB934001 ), National Natural Science Foundation of China ( 51074011 and 51274017 ) and National 863 Program ( 2007AA03Z231 and 2011AA11A257 ).
Funders | Funder number |
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National Natural Science Foundation of China | 51274017, 51074011 |
National High-tech Research and Development Program | 2007AA03Z231, 2011AA11A257 |
National Key Research and Development Program of China | 2013CB934001 |
Keywords
- Cathode
- Li-ion battery
- Li-rich layered material