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Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

  • Sanae El Ghachtouli
  • , H. Y. Vincent Ching
  • , Benedikt Lassalle-Kaiser
  • , Régis Guillot
  • , Domenick F. Leto
  • , Swarup Chattopadhyay
  • , Timothy A. Jackson
  • , Pierre Dorlet
  • , Elodie Anxolabéhère-Mallart

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

Original languageEnglish
Pages (from-to)5696-5698
Number of pages3
JournalChemical Communications
Volume49
Issue number50
DOIs
StatePublished - May 28 2013
Externally publishedYes

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