Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

Sanae El Ghachtouli; H. Y. Vincent Ching; Benedikt Lassalle-Kaiser; Régis Guillot; Domenick F. Leto; Swarup Chattopadhyay; Timothy A. Jackson; Pierre Dorlet; Elodie Anxolabéhère-Mallart

doi:10.1039/c3cc41300d

Electrochemical formation of Mn^III-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

Sanae El Ghachtouli, H. Y. Vincent Ching, Benedikt Lassalle-Kaiser, Régis Guillot, Domenick F. Leto, Swarup Chattopadhyay, Timothy A. Jackson, Pierre Dorlet, Elodie Anxolabéhère-Mallart

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A novel and efficient method for preparing [Mn^III(O₂)(L)]⁺ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

Original language	English
Pages (from-to)	5696-5698
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	50
DOIs	https://doi.org/10.1039/c3cc41300d
State	Published - May 28 2013
Externally published	Yes

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title = "Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands",

abstract = "A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.",

author = "{El Ghachtouli}, Sanae and {Vincent Ching}, {H. Y.} and Benedikt Lassalle-Kaiser and R{\'e}gis Guillot and Leto, {Domenick F.} and Swarup Chattopadhyay and Jackson, {Timothy A.} and Pierre Dorlet and Elodie Anxolab{\'e}h{\`e}re-Mallart",

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doi = "10.1039/c3cc41300d",

language = "English",

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T1 - Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

AU - El Ghachtouli, Sanae

AU - Vincent Ching, H. Y.

AU - Lassalle-Kaiser, Benedikt

AU - Guillot, Régis

AU - Leto, Domenick F.

AU - Chattopadhyay, Swarup

AU - Jackson, Timothy A.

AU - Dorlet, Pierre

AU - Anxolabéhère-Mallart, Elodie

PY - 2013/5/28

Y1 - 2013/5/28

N2 - A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

AB - A novel and efficient method for preparing [MnIII(O2)(L)]+ complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

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U2 - 10.1039/c3cc41300d

DO - 10.1039/c3cc41300d

M3 - Article

C2 - 23689474

AN - SCOPUS:84878634926

SN - 1359-7345

VL - 49

SP - 5696

EP - 5698

JO - Chemical Communications

JF - Chemical Communications

IS - 50

ER -

Electrochemical formation of Mn^III-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

Abstract

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