Electrochemical and solid-state lithiation of graphitic C3N 4

Gabriel M. Veith, Loïc Baggetto, Leslie A. Adamczyk, Bingkun Guo, Suree S. Brown, Xiao Guang Sun, Austin A. Albert, James R. Humble, Craig E. Barnes, Michael J. Bojdys, Sheng Dai, Nancy J. Dudney

Research output: Contribution to journalArticlepeer-review

142 Scopus citations

Abstract

Lithiated graphitic carbon nitride (C3N4) was fabricated by electrochemical and solid-state reactions. The addition of Li to C3N4 results in a reaction between the Li and the graphite-like C3N species in C3N4. This irreversible reaction leads to the formation of Li-CH=NR and Li-N=CR2 species, which are detrimental to anode properties. Suitable nitrogen-doped carbon structures for anode applications are predicted to need high concentrations of pyridinic C-N-C terminal bonds and low concentrations of quaternary C3N species to boost electronic conductivity and reversibly cycle Li ions.

Original languageEnglish
Pages (from-to)503-508
Number of pages6
JournalChemistry of Materials
Volume25
Issue number3
DOIs
StatePublished - Feb 12 2013

Keywords

  • anode
  • battery
  • carbon nitride
  • lithiation

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