Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Ivan Vlassiouk; Sergei Smirnov

doi:10.1021/jp034095d

Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Ivan Vlassiouk
, Sergei Smirnov

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

Original language	English
Pages (from-to)	7561-7566
Number of pages	6
Journal	Journal of Physical Chemistry A
Volume	107
Issue number	38
DOIs	https://doi.org/10.1021/jp034095d
State	Published - Sep 25 2003
Externally published	Yes

Access to Document

10.1021/jp034095d

Cite this

@article{ab04d557e8f44143a88a45f86fbd9c90,

title = "Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules",

abstract = "A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.",

author = "Ivan Vlassiouk and Sergei Smirnov",

year = "2003",

month = sep,

day = "25",

doi = "10.1021/jp034095d",

language = "English",

volume = "107",

pages = "7561--7566",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "38",

}

TY - JOUR

T1 - Electric Polarization of Dilute Polar Solutions

T2 - Revised Treatment for Arbitrary Shaped Molecules

AU - Vlassiouk, Ivan

AU - Smirnov, Sergei

PY - 2003/9/25

Y1 - 2003/9/25

N2 - A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

AB - A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

UR - https://www.scopus.com/pages/publications/0141890774

U2 - 10.1021/jp034095d

DO - 10.1021/jp034095d

M3 - Article

AN - SCOPUS:0141890774

SN - 1089-5639

VL - 107

SP - 7561

EP - 7566

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 38

ER -

Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Abstract

Access to Document

Other files and links

Fingerprint

Cite this