Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Ivan Vlassiouk; Sergei Smirnov

doi:10.1021/jp034095d

Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Ivan Vlassiouk, Sergei Smirnov

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Abstract

A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

Original language	English
Pages (from-to)	7561-7566
Number of pages	6
Journal	Journal of Physical Chemistry A
Volume	107
Issue number	38
DOIs	https://doi.org/10.1021/jp034095d
State	Published - Sep 25 2003
Externally published	Yes

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title = "Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules",

abstract = "A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.",

author = "Ivan Vlassiouk and Sergei Smirnov",

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T1 - Electric Polarization of Dilute Polar Solutions

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AU - Smirnov, Sergei

PY - 2003/9/25

Y1 - 2003/9/25

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AB - A model for deducing dipole moments of solute molecules from the electric polarization of dilute solutions is revised. The treatment represents a modified Onsager model extended toward arbitrary-shaped molecules. A simplified approach for data evaluation is suggested and compared with the analytical solution for an ellipsoidal cavity and with a numerical solution for two spherical ions.

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U2 - 10.1021/jp034095d

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JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 38

ER -

Electric Polarization of Dilute Polar Solutions: Revised Treatment for Arbitrary Shaped Molecules

Abstract

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