Elastic yielding in entangled polymeric liquids: Exploring origin of flow inhomogeneity

Shi Qing Wang, P. E. Boukany, S. Ravindranath, Y. Y. Wang, X. Li

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

We will present an overview of the latest developments in the area of nonlinear flow behavior of entangled polymer solutions and melts, on both experimental and theoretical fronts. From visualization-based experiments, we have derived a theoretical understanding of a host of striking flow phenomena ranging from elastic breakdown after a step strain, to emergence of shear inhomogeneity in startup and large amplitude oscillatory shear to universal scaling behavior associated with the yield point identified to be the force maximum during start flow. In this presentation, we address basic questions such as (a) where cohesion comes from in polymeric liquids, (b) how cohesive failure occurs during startup flow and after step flow respectively, (c) whether and how well entangled polymers as transient solids break up inhomogeneously first before forced to undergo subsequent continual deformation. Clearly, effects of chain entanglement are not only dynamical as recognized in the past but also mechanical, and we must be concerned about the cohesive strength of such "solids". The new picture has allowed us to depict and analyze both simple shear and uniaxial extension behaviors in a unified manner.

Original languageEnglish
Title of host publicationThe XVth International Congress on Rheology - The Society of Rheology 80th Annual Meeting
Pages397-399
Number of pages3
DOIs
StatePublished - 2008
Externally publishedYes
Event15th International Congress on Rheology - Monterey, CA, United States
Duration: Aug 3 2008Aug 8 2008

Publication series

NameAIP Conference Proceedings
Volume1027
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference15th International Congress on Rheology
Country/TerritoryUnited States
CityMonterey, CA
Period08/3/0808/8/08

Keywords

  • Cohesion of entanglement network
  • Elastic yielding
  • Necking in extension
  • Particle-tracking velocimetry
  • Plastic flow
  • Shear banding

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