Efficient sulfur-tolerant bimetallic catalysts for hydrogen generation from diesel fuel

Praveen K. Cheekatamarla; Alan M. Lane

doi:10.1016/j.jpowsour.2005.03.176

Efficient sulfur-tolerant bimetallic catalysts for hydrogen generation from diesel fuel

Praveen K. Cheekatamarla
, Alan M. Lane

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Catalytic autothermal reforming (ATR) of synthetic diesel and JP8 over supported metal catalysts has been investigated in the present study. Bimetallic catalysts exhibited superior performance compared to the commercial catalyst and the monometallic counterparts. BET, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR) and XPS were utilized for characterizing these formulations, which showed that the enhanced stability is due to a strong metal-metal and metal-support interaction in the catalyst.

Original language	English
Pages (from-to)	157-164
Number of pages	8
Journal	Journal of Power Sources
Volume	153
Issue number	1
DOIs	https://doi.org/10.1016/j.jpowsour.2005.03.176
State	Published - Jan 23 2006
Externally published	Yes

Funding

This project was supported by Argonne National Laboratory. Helpful discussions with Dr. Theodore Krause are gratefully acknowledged.

Keywords

Autothermal
Diesel
Fuel cells
Hydrogen
Reforming
Sulfur

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10.1016/j.jpowsour.2005.03.176

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title = "Efficient sulfur-tolerant bimetallic catalysts for hydrogen generation from diesel fuel",

abstract = "Catalytic autothermal reforming (ATR) of synthetic diesel and JP8 over supported metal catalysts has been investigated in the present study. Bimetallic catalysts exhibited superior performance compared to the commercial catalyst and the monometallic counterparts. BET, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR) and XPS were utilized for characterizing these formulations, which showed that the enhanced stability is due to a strong metal-metal and metal-support interaction in the catalyst.",

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AU - Cheekatamarla, Praveen K.

AU - Lane, Alan M.

PY - 2006/1/23

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N2 - Catalytic autothermal reforming (ATR) of synthetic diesel and JP8 over supported metal catalysts has been investigated in the present study. Bimetallic catalysts exhibited superior performance compared to the commercial catalyst and the monometallic counterparts. BET, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR) and XPS were utilized for characterizing these formulations, which showed that the enhanced stability is due to a strong metal-metal and metal-support interaction in the catalyst.

AB - Catalytic autothermal reforming (ATR) of synthetic diesel and JP8 over supported metal catalysts has been investigated in the present study. Bimetallic catalysts exhibited superior performance compared to the commercial catalyst and the monometallic counterparts. BET, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR) and XPS were utilized for characterizing these formulations, which showed that the enhanced stability is due to a strong metal-metal and metal-support interaction in the catalyst.

KW - Autothermal

KW - Diesel

KW - Fuel cells

KW - Hydrogen

KW - Reforming

KW - Sulfur

UR - https://www.scopus.com/pages/publications/30144438904

U2 - 10.1016/j.jpowsour.2005.03.176

DO - 10.1016/j.jpowsour.2005.03.176

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EP - 164

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 1

ER -

Efficient sulfur-tolerant bimetallic catalysts for hydrogen generation from diesel fuel

Abstract

Funding

Keywords

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