Efficient CO2 capture by a 3D porous polymer derived from tröger's base

Xiang Zhu; Chi Linh Do-Thanh; Christopher R. Murdock; Kimberly M. Nelson; Chengcheng Tian; Suree Brown; Shannon M. Mahurin; David M. Jenkins; Jun Hu; Bin Zhao; Honglai Liu; Sheng Dai

doi:10.1021/mz4003485

Efficient CO₂ capture by a 3D porous polymer derived from tröger's base

Xiang Zhu, Chi Linh Do-Thanh, Christopher R. Murdock, Kimberly M. Nelson, Chengcheng Tian, Suree Brown, Shannon M. Mahurin, David M. Jenkins, Jun Hu, Bin Zhao, Honglai Liu, Sheng Dai

Research output: Contribution to journal › Article › peer-review

135 Scopus citations

Abstract

A 3D Tröger's-base-derived microporous organic polymer with a high surface area and good thermal stability was facilely synthesized from a one-pot metal-free polymerization reaction between dimethoxymethane and triaminotriptycene. The obtained material displays excellent CO₂ uptake abilities as well as good adsorption selectivity for CO₂ over N₂. The CO₂ storage can reach up to 4.05 mmol g ^-1 (17.8 wt %) and 2.57 mmol g^-1 (11.3 wt %) at 273 K and 298 K, respectively. Moreover, the high selectivity of the polymer toward CO₂ over N₂ (50.6, 298 K) makes it a promising material for potential application in CO₂ separation from flue gas.

Original language	English
Pages (from-to)	660-663
Number of pages	4
Journal	ACS Macro Letters
Volume	2
Issue number	8
DOIs	https://doi.org/10.1021/mz4003485
State	Published - Aug 20 2013

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title = "Efficient CO2 capture by a 3D porous polymer derived from tr{\"o}ger's base",

abstract = "A 3D Tr{\"o}ger's-base-derived microporous organic polymer with a high surface area and good thermal stability was facilely synthesized from a one-pot metal-free polymerization reaction between dimethoxymethane and triaminotriptycene. The obtained material displays excellent CO2 uptake abilities as well as good adsorption selectivity for CO2 over N2. The CO2 storage can reach up to 4.05 mmol g -1 (17.8 wt %) and 2.57 mmol g-1 (11.3 wt %) at 273 K and 298 K, respectively. Moreover, the high selectivity of the polymer toward CO2 over N2 (50.6, 298 K) makes it a promising material for potential application in CO2 separation from flue gas.",

author = "Xiang Zhu and Do-Thanh, {Chi Linh} and Murdock, {Christopher R.} and Nelson, {Kimberly M.} and Chengcheng Tian and Suree Brown and Mahurin, {Shannon M.} and Jenkins, {David M.} and Jun Hu and Bin Zhao and Honglai Liu and Sheng Dai",

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doi = "10.1021/mz4003485",

language = "English",

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T1 - Efficient CO2 capture by a 3D porous polymer derived from tröger's base

AU - Zhu, Xiang

AU - Do-Thanh, Chi Linh

AU - Murdock, Christopher R.

AU - Nelson, Kimberly M.

AU - Tian, Chengcheng

AU - Brown, Suree

AU - Mahurin, Shannon M.

AU - Jenkins, David M.

AU - Hu, Jun

AU - Zhao, Bin

AU - Liu, Honglai

AU - Dai, Sheng

PY - 2013/8/20

Y1 - 2013/8/20

N2 - A 3D Tröger's-base-derived microporous organic polymer with a high surface area and good thermal stability was facilely synthesized from a one-pot metal-free polymerization reaction between dimethoxymethane and triaminotriptycene. The obtained material displays excellent CO2 uptake abilities as well as good adsorption selectivity for CO2 over N2. The CO2 storage can reach up to 4.05 mmol g -1 (17.8 wt %) and 2.57 mmol g-1 (11.3 wt %) at 273 K and 298 K, respectively. Moreover, the high selectivity of the polymer toward CO2 over N2 (50.6, 298 K) makes it a promising material for potential application in CO2 separation from flue gas.

AB - A 3D Tröger's-base-derived microporous organic polymer with a high surface area and good thermal stability was facilely synthesized from a one-pot metal-free polymerization reaction between dimethoxymethane and triaminotriptycene. The obtained material displays excellent CO2 uptake abilities as well as good adsorption selectivity for CO2 over N2. The CO2 storage can reach up to 4.05 mmol g -1 (17.8 wt %) and 2.57 mmol g-1 (11.3 wt %) at 273 K and 298 K, respectively. Moreover, the high selectivity of the polymer toward CO2 over N2 (50.6, 298 K) makes it a promising material for potential application in CO2 separation from flue gas.

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JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 8

ER -

Efficient CO₂ capture by a 3D porous polymer derived from tröger's base

Abstract

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