Effect of oxygen nonstoichiometry on structural and magnetic properties of Ho0.1Sr0.9CoO3-x perovskites (0.15≤x≤0.49)

S. Streule, A. Podlesnyak, J. Mesot, K. Conder, N. Golosova, E. Mitberg, S. Kazakov

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Abstract

Results of neutron diffraction and bulk magnetic measurements on powder samples Ho0.1Sr0.9CoO3-x as a function of oxygen deficiency 0.15<x<0.49 are given. It is found that the oxygen non-stoichiometry affects the crystal and magnetic structures as well as the value of the magnetic moment, and strongly modifies the magnetic ordering temperatures.

Original languageEnglish
Pages (from-to)e281-e284
JournalPhysica B: Physics of Condensed Matter
Volume350
Issue number1-3 SUPPL. 1
DOIs
StatePublished - Jul 15 2004
Externally publishedYes

Funding

This work was performed at the spallation neutron source SINQ of the Paul Scherrer Institute, Switzerland. The authors thank the Swiss National Science Foundation for financial support through grants SCOPES No. 7 BYPJ 065732 and 200021-100194, as well as NCCR MaNEP project. Financial support by the INTAS (project No. 278) is also gratefully acknowledged.

Keywords

  • Cobaltites
  • Magnetism
  • Neutron scattering
  • Perovskite structure

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