Abstract
The relationship between carrier concentration, structure and composition in Bi2Sr2CaCu2O8+δ is amongst the most complex of the high-Tc superconducting cuprates. In this paper a number of structural subtleties of the system are discussed based on the results of high-resolution X-ray scattering measurements from single crystals. It is found that the annealing of an oxygen-rich crystal significantly changes the character of certain diffuse scattering features. Accompanying analysis of composition and measurements of Tc suggest these changes may be the signature of oxygen ordering which is influential to the superconductivity.
Original language | English |
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Pages (from-to) | 240-248 |
Number of pages | 9 |
Journal | Physica C: Superconductivity and its Applications |
Volume | 299 |
Issue number | 3-4 |
DOIs | |
State | Published - Apr 20 1998 |
Externally published | Yes |
Funding
We are grateful to H. Vass for his technical assistance in this experiment. Financial support was provided by the Engineering and Physical Sciences Research Council. STJ is grateful to the Department of Social Security for support during the writing of this paper, and to the School of Physics, The University of Birmingham for hosting its completion.
Funders | Funder number |
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Engineering and Physical Sciences Research Council |
Keywords
- Modulated structures
- Oxygen vacancies
- Structural phase transformation
- Structure of BiSrCaCuO
- X-ray diffraction