Abstract
Subsize dogbone tensile specimens of alloys 304H, 310HCbN, and 740H were exposed to 30 MPa supercritical CO2 (sCO2) for up to 4000 h at 750°C. Similar exposures in laboratory air were used to assess the specific role of sCO2 exposure on the alloy tensile properties. Type 304H specimens were only embrittled by exposure in sCO2 due to the formation of a thick Fe-rich oxide and C ingress in the bulk of the alloy. For 310HCbN and 740H, no effect of the sCO2 environment was observed and a decrease of the alloy's ductility was associated with previously observed microstructure evolutions, for example, grain boundary carbide formation. The 740H was tested in the solution annealed condition and self-aging took place during 750°C exposures in sCO2 and air with the formation of fine gamma prime precipitates leading to significant tensile strength increase. It was found that both 740H and 310HCbN have adequate sCO2 compatibility for high-temperature commercial applications.
| Original language | English |
|---|---|
| Pages (from-to) | 497-512 |
| Number of pages | 16 |
| Journal | Materials and Corrosion |
| Volume | 73 |
| Issue number | 4 |
| DOIs | |
| State | Published - Apr 2022 |
Funding
The authors would like to thank V. Cox and T. M. Lowe for their assistance with the experimental work and E. Lara-Curzio and M. Romedenne for comments on the manuscript. This study has been carried out partly within the Academy of Finland project “Novel Approaches to Study Corrosion Mechanisms in High-temperature Industrial Processes” (Decision no. 296435). This study was sponsored by the U.S. Department of Energy, Office of Fossil Energy, Crosscutting Technology Program. This manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan). The authors would like to thank V. Cox and T. M. Lowe for their assistance with the experimental work and E. Lara‐Curzio and M. Romedenne for comments on the manuscript. This study has been carried out partly within the Academy of Finland project “Novel Approaches to Study Corrosion Mechanisms in High‐temperature Industrial Processes” (Decision no. 296435). This study was sponsored by the U.S. Department of Energy, Office of Fossil Energy, Crosscutting Technology Program. This manuscript has been authored by UT‐Battelle, LLC under Contract No. DE‐AC05‐00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid‐up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ).
Keywords
- carburization
- structural alloys
- supercritical CO
- tensile properties