Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides

Jerred J. Russell; Joseph F. DeJesus; Brett A. Smith; Phattananawee Nalaoh; Konstantinos D. Vogiatzis; David M. Jenkins

doi:10.1039/d4dt01422g

Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides

Jerred J. Russell, Joseph F. DeJesus, Brett A. Smith, Phattananawee Nalaoh, Konstantinos D. Vogiatzis, David M. Jenkins

Chemical Sciences Division

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Abstract

A chiral tetra-NHC iron(ii) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(ii) complex yielding three distinct products: an iron(iv) imide, an iron(iv) tetrazene, and a surprising and unprecedented double imide insertion complex.

Original language	English
Pages (from-to)	10819-10823
Number of pages	5
Journal	Dalton Transactions
Volume	53
Issue number	26
DOIs	https://doi.org/10.1039/d4dt01422g
State	Published - Jun 12 2024

Funding

The authors thank the National Science Foundation (NSF CHE-2154697) and NIH (R15GM117494-02) for support. We also thank the Infrastructure for Scientific Applications and Advanced Computing (ISAAC) for computational resources and the University of Tennessee for additional support. Any opinions, findings, and conclusions expressed in this material are those of the authors and do not necessarily reflect the views of the National Science Foundation.

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10.1039/d4dt01422g

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title = "Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides",

abstract = "A chiral tetra-NHC iron(ii) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(ii) complex yielding three distinct products: an iron(iv) imide, an iron(iv) tetrazene, and a surprising and unprecedented double imide insertion complex.",

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AU - Russell, Jerred J.

AU - DeJesus, Joseph F.

AU - Smith, Brett A.

AU - Nalaoh, Phattananawee

AU - Vogiatzis, Konstantinos D.

AU - Jenkins, David M.

PY - 2024/6/12

Y1 - 2024/6/12

N2 - A chiral tetra-NHC iron(ii) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(ii) complex yielding three distinct products: an iron(iv) imide, an iron(iv) tetrazene, and a surprising and unprecedented double imide insertion complex.

AB - A chiral tetra-NHC iron(ii) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(ii) complex yielding three distinct products: an iron(iv) imide, an iron(iv) tetrazene, and a surprising and unprecedented double imide insertion complex.

UR - https://www.scopus.com/pages/publications/85196008602

U2 - 10.1039/d4dt01422g

DO - 10.1039/d4dt01422g

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AN - SCOPUS:85196008602

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VL - 53

SP - 10819

EP - 10823

JO - Dalton Transactions

JF - Dalton Transactions

IS - 26

ER -

Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides

Abstract

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