Dislocations in PbTiO3 Thin Films

S. Stemmer, S. K. Streiffer, F. Ernst, M. Rühle

Research output: Contribution to journalArticlepeer-review

69 Scopus citations

Abstract

Using conventional and high resolution transmission electron microscopy, the dislocation structures in PbTiO3 thin films grown epitaxially on [001]‐oriented MgO and SrTiO3 single crystals are studied. High resolution cross‐sectional images of the films grown on MgO exhibit misfit dislocations with Burgers vectors of 1/2 〈010〉 and line directions of 〈100〉. The latter are identified by imaging the interface in two non‐parallel zone axes. Plan‐view studies of films grown on SrTiO3 reveal dislocations with Burgers vectors of 〈010〉 lying along 〈100〉 directions in the plane of the film. High resolution microscopy of cross‐sectional samples shows dislocations in these films that have the additional half‐plane on the substrate side of the film, opposite to what is required to accommodate the lattice misfit at room temperature. The mechanisms for dislocation formation and the role of the dislocations in stress relaxation with respect to the competing mechanism of 90° domain formation are discussed.

Original languageEnglish
Pages (from-to)135-154
Number of pages20
JournalPhysica Status Solidi (A) Applied Research
Volume147
Issue number1
DOIs
StatePublished - Jan 16 1995
Externally publishedYes

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