Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS

Wenyang Zhang; Chengbo Zhou; Yao Zhang; Feifei Xue; Baojing Luo; Hongfei Li; Xiangkui Ren; Jingqing Li; Yingrui Shang; Zhonghua Wu; Shichun Jiang

doi:10.1007/s00396-015-3789-z

Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS

Wenyang Zhang, Chengbo Zhou, Yao Zhang, Feifei Xue, Baojing Luo, Hongfei Li, Xiangkui Ren, Jingqing Li, Yingrui Shang, Zhonghua Wu, Shichun Jiang

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9 Scopus citations

Abstract

The deformation behavior is closely related to the structures and mechanical properties of polymers. The structural evolution during deformation is fundamental to understand the deformation mechanism and control the properties of polymers. Deformation-induced structure transitions contain a stable structure to metastable one or metastable structure to a stable one. The structures of the uniaxially stretched poly(butylene succinate) (PBS) at different temperatures were directly investigated by in situ synchrotron wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). The data reveal the initial strain of the α-β transition increases with the stretching temperatures. A quantitative analysis was performed to explore the crystal transition mechanisms of the stretched PBS.

Original language	English
Pages (from-to)	321-328
Number of pages	8
Journal	Colloid and Polymer Science
Volume	294
Issue number	2
DOIs	https://doi.org/10.1007/s00396-015-3789-z
State	Published - Feb 1 2016
Externally published	Yes

Funding

This work was supported by the National Natural Science Foundation of China (51173130, 21274149, and 21374077).

Keywords

Poly(butylene succinate) deformation
SAXS and WAXS in situ investigations
Structure transitions

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10.1007/s00396-015-3789-z

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title = "Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS",

abstract = "The deformation behavior is closely related to the structures and mechanical properties of polymers. The structural evolution during deformation is fundamental to understand the deformation mechanism and control the properties of polymers. Deformation-induced structure transitions contain a stable structure to metastable one or metastable structure to a stable one. The structures of the uniaxially stretched poly(butylene succinate) (PBS) at different temperatures were directly investigated by in situ synchrotron wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). The data reveal the initial strain of the α-β transition increases with the stretching temperatures. A quantitative analysis was performed to explore the crystal transition mechanisms of the stretched PBS.",

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AU - Zhang, Wenyang

AU - Zhou, Chengbo

AU - Zhang, Yao

AU - Xue, Feifei

AU - Luo, Baojing

AU - Li, Hongfei

AU - Ren, Xiangkui

AU - Li, Jingqing

AU - Shang, Yingrui

AU - Wu, Zhonghua

AU - Jiang, Shichun

PY - 2016/2/1

Y1 - 2016/2/1

N2 - The deformation behavior is closely related to the structures and mechanical properties of polymers. The structural evolution during deformation is fundamental to understand the deformation mechanism and control the properties of polymers. Deformation-induced structure transitions contain a stable structure to metastable one or metastable structure to a stable one. The structures of the uniaxially stretched poly(butylene succinate) (PBS) at different temperatures were directly investigated by in situ synchrotron wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). The data reveal the initial strain of the α-β transition increases with the stretching temperatures. A quantitative analysis was performed to explore the crystal transition mechanisms of the stretched PBS.

AB - The deformation behavior is closely related to the structures and mechanical properties of polymers. The structural evolution during deformation is fundamental to understand the deformation mechanism and control the properties of polymers. Deformation-induced structure transitions contain a stable structure to metastable one or metastable structure to a stable one. The structures of the uniaxially stretched poly(butylene succinate) (PBS) at different temperatures were directly investigated by in situ synchrotron wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS). The data reveal the initial strain of the α-β transition increases with the stretching temperatures. A quantitative analysis was performed to explore the crystal transition mechanisms of the stretched PBS.

KW - Poly(butylene succinate) deformation

KW - SAXS and WAXS in situ investigations

KW - Structure transitions

UR - https://www.scopus.com/pages/publications/84956703653

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DO - 10.1007/s00396-015-3789-z

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JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

IS - 2

ER -

Direct investigations of temperature related structure transitions in strained poly(butylene succinate) with SAXS and WAXS

Abstract

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