Dielectric spectroscopy investigation of relaxation in c60-polyisoprene nanocomposites

Yifu Ding, Sebastian Pawlus, Alexei P. Sokolov, Jack F. Douglas, Alamgir Karim, Christopher L. Soles

Research output: Contribution to journalArticlepeer-review

60 Scopus citations

Abstract

We investigate the in influence of adding C60 nanoparticles on the dielectric relaxation spectra of both unentangled and entangled polyisoprene (PIP). Relaxation modes corresponding to both the segmental and chain relaxation were analyzed over a broad temperature and frequency range. Regardless of whether the chains were entangled or not, both relaxation processes slowed down with the addition of C60, rejecting an increase of the nanocomposite glass transition temperature. However, C60 affects the segmental relaxation more strongly than the large-scale chain relaxation, both in terms of the relaxation time and strength, suggesting that the effect of the nanoparticles on the polymer dynamics is scale dependent. This effect is attributed to a difference in packing frustration at different length scales, a phenomenon also relevant to understanding the difference between the temperature dependence of the segmental and chain relaxation processes in neat polymer materials. Further evidence of this scale dependence is indicated by the observation that the secondary relaxation time of the high molecular mass PIP decreases with an addition of C60. These observations indicate that C60 has an effect opposite to antiplasticizing additives that slow down the secondary relaxation (stiffening the material) in the glass state, while at the same time reducing the alpha relaxation time associated with cooperative segmental and chain motions. Recent incoherent neutron scattering measurements have indicated that C can have a similar effect on polystyrene.

Original languageEnglish
Pages (from-to)3201-3206
Number of pages6
JournalMacromolecules
Volume42
Issue number8
DOIs
StatePublished - Apr 28 2009
Externally publishedYes

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