Dicaesium magnesium bis-(dihydrogen phosphate(V)) dihydrate

Rachid Essehli; Brahim El Bali; Mohammed Lachkar; Michael Bolte

doi:10.1107/S1600536808042384

Dicaesium magnesium bis-(dihydrogen phosphate(V)) dihydrate

Rachid Essehli, Brahim El Bali, Mohammed Lachkar, Michael Bolte

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Abstract

The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs⁺ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg²⁺ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.

Original language	English
Pages (from-to)	i3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	1
DOIs	https://doi.org/10.1107/S1600536808042384
State	Published - 2008

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abstract = "The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs+ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg2+ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.",

author = "Rachid Essehli and \{El Bali\}, Brahim and Mohammed Lachkar and Michael Bolte",

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T1 - Dicaesium magnesium bis-(dihydrogen phosphate(V)) dihydrate

AU - Essehli, Rachid

AU - El Bali, Brahim

AU - Lachkar, Mohammed

AU - Bolte, Michael

PY - 2008

Y1 - 2008

N2 - The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs+ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg2+ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.

AB - The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs+ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg2+ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.

UR - https://www.scopus.com/pages/publications/58149474514

U2 - 10.1107/S1600536808042384

DO - 10.1107/S1600536808042384

M3 - Article

AN - SCOPUS:58149474514

SN - 1600-5368

VL - 65

SP - i3

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 1

ER -

Dicaesium magnesium bis-(dihydrogen phosphate(V)) dihydrate

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