Development of a Corrosion Monitoring System for Advanced Molten Salt Reactors

Molten salt reactors (MSRs) have been identified as one of several possible next-generation advanced reactor designs that could replace the aging fleet. There are many inherent advantages to MSRs, including higher power density, lower pressure, low stored energy, and prompt negative temperature reactivity coefficient Ezell et al. [2018]. However, there are challenges related to the operating temperatures, as well as, the corrosive salts attacking the structural materials. During the Molten Salt Reactor Experiment (MSRE), which was operated at Oak Ridge National Laboratory (ORNL) (Ignatiev et al. [2014], Forsberg et al. [2007], Forsberg et al. [2008], Delpech et al. [2009], Serp et al. [2014], Ignatiev and Surenkov [2017]) corrosion was monitored by sampling the salt for chromium. However, this type of monitoring does not identify the location of corrosion. In FY18, ORNL developed a novel in-situ corrosion sensor that could be placed on the outside of the structure to monitor changes in magnetic susceptibility of salt-wetted alloys as corrosion occurs Holcomb et al. [2019]. Initial testing with this novel sensor demonstrated a correlation between the change in signal output from the sensor to the various levels of pre-corroded test specimens. However, all initial testing was performed at room temperatures, which is not realistic for the harsh MSR environment. Based on this research, FY19 funding allowed for development of a high-temperature version of the sensor to be installed at various locations on the reactor infrastructure. The high-temperature sensor can operate at up to 750°C and can monitor development of corrosion inside the pipe. This sensor measures the increase in magnetic susceptibility that occurs as chromium dissolves from the inner surface of the pipe, when paramagnetic structural alloys become ferromagnetic with the loss of chromium. This report will discuss the development of corrosion monitoring sensor and the testing with results of corroded specimens at increasing temperatures.