Determining P, S, Br, and I content in uranium by triple quadrupole inductively coupled plasma mass spectrometry

Nathaniel D. Fletcher, Benjamin T. Manard, Shalina C. Metzger, Brian W. Ticknor, Debra A. Bostick, Cole R. Hexel

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

The trace impurities of a uranium ore concentrate (UOC) can be examined to determine mine source, methods of production, and quality. This study presents a method to determine the concentration of halides and main group elements, specifically P, S, Br and I, utilizing triple quadrupole inductively coupled plasma–mass spectrometry. These analytes were measured in a uranium matrix to simulate a UOC sample. The concentrations determined with this method showed agreement with known values. Solutions with and without uranium were compared. A UOC certified reference material, CUP-2, was analyzed to further demonstrate the effectiveness of the method.

Original languageEnglish
Pages (from-to)395-402
Number of pages8
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume324
Issue number1
DOIs
StatePublished - Apr 1 2020

Funding

This work was supported by the Department of Energy’s National Nuclear Security Administration under contract DE-AC05-00OR22725 with UT-Battelle, LLC. Oak Ridge National Laboratory is managed by UT-Battelle for the Department of Energy under Contract DE-AC05-000R22725. The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US government purposes. DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ). This work was supported by the Department of Energy?s National Nuclear Security Administration under contract DE-AC05-00OR22725 with UT-Battelle, LLC. Oak Ridge National Laboratory is managed by UT-Battelle for the Department of Energy under Contract DE-AC05-000R22725. The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US government purposes. DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).

FundersFunder number
DOE Public Access Plan
UT-Battelle
U.S. Department of EnergyDE-AC05-000R22725
National Nuclear Security AdministrationDE-AC05-00OR22725
Oak Ridge National Laboratory

    Keywords

    • Anions
    • Triple quadrupole inductively coupled plasma—mass spectrometry
    • Uranium matrix
    • Uranium ore concentrate

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