Detection of indentation induced FE-to-AFE phase transformation in lead zirconate titanate

Thomas F. Juliano; Yury G. Gogotsi; Thomas E. Buchheit; Chad S. Watson; Sergei V. Kalinin; Junsoo Shin; Arthur P. Baddorf

doi:10.1111/j.1551-2916.2006.01255.x

Detection of indentation induced FE-to-AFE phase transformation in lead zirconate titanate

Thomas F. Juliano, Yury G. Gogotsi, Thomas E. Buchheit, Chad S. Watson, Sergei V. Kalinin, Junsoo Shin, Arthur P. Baddorf

Scanning Tunneling Microscopy Group

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 μm were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.

Original language	English
Pages (from-to)	3557-3559
Number of pages	3
Journal	Journal of the American Ceramic Society
Volume	89
Issue number	11
DOIs	https://doi.org/10.1111/j.1551-2916.2006.01255.x
State	Published - Nov 2006

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title = "Detection of indentation induced FE-to-AFE phase transformation in lead zirconate titanate",

abstract = "Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 μm were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.",

author = "Juliano, {Thomas F.} and Gogotsi, {Yury G.} and Buchheit, {Thomas E.} and Watson, {Chad S.} and Kalinin, {Sergei V.} and Junsoo Shin and Baddorf, {Arthur P.}",

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T1 - Detection of indentation induced FE-to-AFE phase transformation in lead zirconate titanate

AU - Juliano, Thomas F.

AU - Gogotsi, Yury G.

AU - Buchheit, Thomas E.

AU - Watson, Chad S.

AU - Kalinin, Sergei V.

AU - Shin, Junsoo

AU - Baddorf, Arthur P.

PY - 2006/11

Y1 - 2006/11

N2 - Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 μm were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.

AB - Instrumented indentation was combined with microscopy and spectroscopy analysis to investigate the local mechanically induced ferroelectric to anti-ferroelectric phase transformation of niobium-modified lead zirconate titanate 95/5. Indentation experiments to a depth of 2 μm were performed using a Berkovich pyramidal three-sided diamond tip. Subsequent Raman spectroscopy and piezoelectric force microscopy revealed that indentation locally induced the ferroelectric to antiferroelectric phase transformation. Piezoelectric force microscopy demonstrated the ability to map the individual phases within and near indented regions on the niobium-modified lead zirconate titanate ceramics.

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SN - 0002-7820

VL - 89

SP - 3557

EP - 3559

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

IS - 11

ER -

Detection of indentation induced FE-to-AFE phase transformation in lead zirconate titanate

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