Depressing the hydrogenation and decomposition reaction in H2O2 synthesis by supporting AuPd on oxygen functionalized carbon nanofibers

Alberto Villa; Simon J. Freakley; Marco Schiavoni; Jennifer K. Edwards; Ceri Hammond; Gabriel M. Veith; Wu Wang; Di Wang; Laura Prati; Nikolaos Dimitratos; Graham J. Hutchings

doi:10.1039/c5cy01880c

Depressing the hydrogenation and decomposition reaction in H₂O₂ synthesis by supporting AuPd on oxygen functionalized carbon nanofibers

Alberto Villa, Simon J. Freakley, Marco Schiavoni, Jennifer K. Edwards, Ceri Hammond, Gabriel M. Veith, Wu Wang, Di Wang, Laura Prati, Nikolaos Dimitratos, Graham J. Hutchings

Energy Storage & Conversion

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24 Scopus citations

Abstract

In this work, we show that the introduction of acidic oxygen functionalities to the surface of carbon nanofibers serves to depress the hydrogenation and the decomposition of hydrogen peroxide during the direct synthesis of H₂O₂. Moreover, the presence of acidic groups enhances the H₂O₂ productivity in the case of supported AuPd nanoparticles.

Original language	English
Pages (from-to)	694-697
Number of pages	4
Journal	Catalysis Science and Technology
Volume	6
Issue number	3
DOIs	https://doi.org/10.1039/c5cy01880c
State	Published - 2016

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Villa, A., Freakley, S. J., Schiavoni, M., Edwards, J. K., Hammond, C., Veith, G. M., Wang, W., Wang, D., Prati, L., Dimitratos, N., & Hutchings, G. J. (2016). Depressing the hydrogenation and decomposition reaction in H₂O₂ synthesis by supporting AuPd on oxygen functionalized carbon nanofibers. Catalysis Science and Technology, 6(3), 694-697. https://doi.org/10.1039/c5cy01880c

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title = "Depressing the hydrogenation and decomposition reaction in H2O2 synthesis by supporting AuPd on oxygen functionalized carbon nanofibers",

abstract = "In this work, we show that the introduction of acidic oxygen functionalities to the surface of carbon nanofibers serves to depress the hydrogenation and the decomposition of hydrogen peroxide during the direct synthesis of H2O2. Moreover, the presence of acidic groups enhances the H2O2 productivity in the case of supported AuPd nanoparticles.",

author = "Alberto Villa and Freakley, {Simon J.} and Marco Schiavoni and Edwards, {Jennifer K.} and Ceri Hammond and Veith, {Gabriel M.} and Wu Wang and Di Wang and Laura Prati and Nikolaos Dimitratos and Hutchings, {Graham J.}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c5cy01880c",

language = "English",

volume = "6",

pages = "694--697",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

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Villa, A, Freakley, SJ, Schiavoni, M, Edwards, JK, Hammond, C, Veith, GM, Wang, W, Wang, D, Prati, L, Dimitratos, N & Hutchings, GJ 2016, 'Depressing the hydrogenation and decomposition reaction in H₂O₂ synthesis by supporting AuPd on oxygen functionalized carbon nanofibers', Catalysis Science and Technology, vol. 6, no. 3, pp. 694-697. https://doi.org/10.1039/c5cy01880c

TY - JOUR

T1 - Depressing the hydrogenation and decomposition reaction in H2O2 synthesis by supporting AuPd on oxygen functionalized carbon nanofibers

AU - Villa, Alberto

AU - Freakley, Simon J.

AU - Schiavoni, Marco

AU - Edwards, Jennifer K.

AU - Hammond, Ceri

AU - Veith, Gabriel M.

AU - Wang, Wu

AU - Wang, Di

AU - Prati, Laura

AU - Dimitratos, Nikolaos

AU - Hutchings, Graham J.

PY - 2016

Y1 - 2016

N2 - In this work, we show that the introduction of acidic oxygen functionalities to the surface of carbon nanofibers serves to depress the hydrogenation and the decomposition of hydrogen peroxide during the direct synthesis of H2O2. Moreover, the presence of acidic groups enhances the H2O2 productivity in the case of supported AuPd nanoparticles.

AB - In this work, we show that the introduction of acidic oxygen functionalities to the surface of carbon nanofibers serves to depress the hydrogenation and the decomposition of hydrogen peroxide during the direct synthesis of H2O2. Moreover, the presence of acidic groups enhances the H2O2 productivity in the case of supported AuPd nanoparticles.

UR - http://www.scopus.com/inward/record.url?scp=84957598048&partnerID=8YFLogxK

U2 - 10.1039/c5cy01880c

DO - 10.1039/c5cy01880c

M3 - Article

AN - SCOPUS:84957598048

SN - 2044-4753

VL - 6

SP - 694

EP - 697

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 3

ER -

Depressing the hydrogenation and decomposition reaction in H₂O₂ synthesis by supporting AuPd on oxygen functionalized carbon nanofibers

Abstract

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