Defect spinels in the system Li2O.yMnO2 (y>2.5): A neutron-diffraction study and electrochemical characterization of Li2Mn4O9

A. de Kock; M. H. Rossouw; L. A. de Picciotto; M. M. Thackeray; W. I.F. David; R. M. Ibberson

doi:10.1016/0025-5408(90)90032-W

Defect spinels in the system Li₂O.yMnO₂ (y>2.5): A neutron-diffraction study and electrochemical characterization of Li₂Mn₄O₉

A. de Kock, M. H. Rossouw, L. A. de Picciotto, M. M. Thackeray, W. I.F. David, R. M. Ibberson

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Abstract

The structure of the defect spinel Li₂Mn₄O₉ which is a component of the system Li₂O.yMnO₂ (y = 4.0) has been determined by neutron diffraction analysis; it has the spinel notation (Li_0.89□0.11) [Mn_1.78□0.22]O₄. The electrochemical properties of Li₂Mn₄O₉ when used as an insertion electrode in rechargeable room-temperature lithium cells have been evaluated.

Original language	English
Pages (from-to)	657-664
Number of pages	8
Journal	Materials Research Bulletin
Volume	25
Issue number	5
DOIs	https://doi.org/10.1016/0025-5408(90)90032-W
State	Published - May 1990
Externally published	Yes

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title = "Defect spinels in the system Li2O.yMnO2 (y>2.5): A neutron-diffraction study and electrochemical characterization of Li2Mn4O9",

abstract = "The structure of the defect spinel Li2Mn4O9 which is a component of the system Li2O.yMnO2 (y = 4.0) has been determined by neutron diffraction analysis; it has the spinel notation (Li0.89□0.11) [Mn1.78□0.22]O4. The electrochemical properties of Li2Mn4O9 when used as an insertion electrode in rechargeable room-temperature lithium cells have been evaluated.",

author = "{de Kock}, A. and Rossouw, {M. H.} and {de Picciotto}, {L. A.} and Thackeray, {M. M.} and David, {W. I.F.} and Ibberson, {R. M.}",

year = "1990",

month = may,

doi = "10.1016/0025-5408(90)90032-W",

language = "English",

volume = "25",

pages = "657--664",

journal = "Materials Research Bulletin",

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number = "5",

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TY - JOUR

T1 - Defect spinels in the system Li2O.yMnO2 (y>2.5)

T2 - A neutron-diffraction study and electrochemical characterization of Li2Mn4O9

AU - de Kock, A.

AU - Rossouw, M. H.

AU - de Picciotto, L. A.

AU - Thackeray, M. M.

AU - David, W. I.F.

AU - Ibberson, R. M.

PY - 1990/5

Y1 - 1990/5

N2 - The structure of the defect spinel Li2Mn4O9 which is a component of the system Li2O.yMnO2 (y = 4.0) has been determined by neutron diffraction analysis; it has the spinel notation (Li0.89□0.11) [Mn1.78□0.22]O4. The electrochemical properties of Li2Mn4O9 when used as an insertion electrode in rechargeable room-temperature lithium cells have been evaluated.

AB - The structure of the defect spinel Li2Mn4O9 which is a component of the system Li2O.yMnO2 (y = 4.0) has been determined by neutron diffraction analysis; it has the spinel notation (Li0.89□0.11) [Mn1.78□0.22]O4. The electrochemical properties of Li2Mn4O9 when used as an insertion electrode in rechargeable room-temperature lithium cells have been evaluated.

UR - http://www.scopus.com/inward/record.url?scp=0025658383&partnerID=8YFLogxK

U2 - 10.1016/0025-5408(90)90032-W

DO - 10.1016/0025-5408(90)90032-W

M3 - Article

AN - SCOPUS:0025658383

SN - 0025-5408

VL - 25

SP - 657

EP - 664

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 5

ER -

Defect spinels in the system Li₂O.yMnO₂ (y>2.5): A neutron-diffraction study and electrochemical characterization of Li₂Mn₄O₉

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