Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene

V. Chandrasekhar; K. Vivekanandan; S. Nagendran; G. T. Senthil Andavan; N. R. Weathers; J. C. Yarbrough; A. W. Cordes

doi:10.1021/ic980520j

Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene

V. Chandrasekhar
, K. Vivekanandan
, S. Nagendran
, G. T. Senthil Andavan
, N. R. Weathers
, J. C. Yarbrough
, A. W. Cordes

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The reactions of chlorocyclophosphazenes N₃P₃Cl₆ (1) and N₄P₄Cl₈ (2) and polydichlorophosphazene (3) with cyclohexylamine, cyclopentylamine, and cyclopropylamine have been studied. The major product with 1 is the geminal tetrakis derivative N₃P₃Cl₂(NHR)₄, while 2 gives the completely substituted derivative, N₄P₄(NHR)₈. X-ray crystal structure determinations of N₃P₃Cl₂(NHC₆H₁₁) ₄ (1a) and N₄P₄(NHC₃H₅)₈ (2c) have been carried out. 1a crystallizes in a triclinic space group, P1, with a = 11.2330(13) Å, b = 11.4269(16) Å, c = 13.4055(12) Å, α = 72.211(10)°, β= 72.150(9)°, γ = 81.777(11)°, V = 1557.3(3) A°³, and Z = 2. 2c crystallizes in a monclinic space group, P2₁/n, with a = 12.433(3) Å, b = 20.484(4) Å, c = 12.645(3) Å, β = 92.81(2)°, V = 1557.3(3) A°³, and Z = 4. The cycloalkylamino-substituted polyphosphazenes contain a small amount of residual chlorine atoms. These have high glass transition temperatures.

Original language	English
Pages (from-to)	6192-6198
Number of pages	7
Journal	Inorganic Chemistry
Volume	37
Issue number	24
DOIs	https://doi.org/10.1021/ic980520j
State	Published - 1998
Externally published	Yes

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Chandrasekhar, V., Vivekanandan, K., Nagendran, S., Senthil Andavan, G. T., Weathers, N. R., Yarbrough, J. C., & Cordes, A. W. (1998). Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene. Inorganic Chemistry, 37(24), 6192-6198. https://doi.org/10.1021/ic980520j

@article{bf385b7f02f541249721020c8869058d,

title = "Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene",

abstract = "The reactions of chlorocyclophosphazenes N3P3Cl6 (1) and N4P4Cl8 (2) and polydichlorophosphazene (3) with cyclohexylamine, cyclopentylamine, and cyclopropylamine have been studied. The major product with 1 is the geminal tetrakis derivative N3P3Cl2(NHR)4, while 2 gives the completely substituted derivative, N4P4(NHR)8. X-ray crystal structure determinations of N3P3Cl2(NHC6H11) 4 (1a) and N4P4(NHC3H5)8 (2c) have been carried out. 1a crystallizes in a triclinic space group, P1, with a = 11.2330(13) {\AA}, b = 11.4269(16) {\AA}, c = 13.4055(12) {\AA}, α = 72.211(10)°, β= 72.150(9)°, γ = 81.777(11)°, V = 1557.3(3) A°3, and Z = 2. 2c crystallizes in a monclinic space group, P21/n, with a = 12.433(3) {\AA}, b = 20.484(4) {\AA}, c = 12.645(3) {\AA}, β = 92.81(2)°, V = 1557.3(3) A°3, and Z = 4. The cycloalkylamino-substituted polyphosphazenes contain a small amount of residual chlorine atoms. These have high glass transition temperatures.",

author = "V. Chandrasekhar and K. Vivekanandan and S. Nagendran and \{Senthil Andavan\}, \{G. T.\} and Weathers, \{N. R.\} and Yarbrough, \{J. C.\} and Cordes, \{A. W.\}",

year = "1998",

doi = "10.1021/ic980520j",

language = "English",

volume = "37",

pages = "6192--6198",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "24",

}

Chandrasekhar, V, Vivekanandan, K, Nagendran, S, Senthil Andavan, GT, Weathers, NR, Yarbrough, JC & Cordes, AW 1998, 'Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene', Inorganic Chemistry, vol. 37, no. 24, pp. 6192-6198. https://doi.org/10.1021/ic980520j

Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene. / Chandrasekhar, V.; Vivekanandan, K.; Nagendran, S. et al.
In: Inorganic Chemistry, Vol. 37, No. 24, 1998, p. 6192-6198.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Cycloalkylaminocyclo- and Polyphosphazenes

T2 - X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene

AU - Chandrasekhar, V.

AU - Vivekanandan, K.

AU - Nagendran, S.

AU - Senthil Andavan, G. T.

AU - Weathers, N. R.

AU - Yarbrough, J. C.

AU - Cordes, A. W.

PY - 1998

Y1 - 1998

N2 - The reactions of chlorocyclophosphazenes N3P3Cl6 (1) and N4P4Cl8 (2) and polydichlorophosphazene (3) with cyclohexylamine, cyclopentylamine, and cyclopropylamine have been studied. The major product with 1 is the geminal tetrakis derivative N3P3Cl2(NHR)4, while 2 gives the completely substituted derivative, N4P4(NHR)8. X-ray crystal structure determinations of N3P3Cl2(NHC6H11) 4 (1a) and N4P4(NHC3H5)8 (2c) have been carried out. 1a crystallizes in a triclinic space group, P1, with a = 11.2330(13) Å, b = 11.4269(16) Å, c = 13.4055(12) Å, α = 72.211(10)°, β= 72.150(9)°, γ = 81.777(11)°, V = 1557.3(3) A°3, and Z = 2. 2c crystallizes in a monclinic space group, P21/n, with a = 12.433(3) Å, b = 20.484(4) Å, c = 12.645(3) Å, β = 92.81(2)°, V = 1557.3(3) A°3, and Z = 4. The cycloalkylamino-substituted polyphosphazenes contain a small amount of residual chlorine atoms. These have high glass transition temperatures.

AB - The reactions of chlorocyclophosphazenes N3P3Cl6 (1) and N4P4Cl8 (2) and polydichlorophosphazene (3) with cyclohexylamine, cyclopentylamine, and cyclopropylamine have been studied. The major product with 1 is the geminal tetrakis derivative N3P3Cl2(NHR)4, while 2 gives the completely substituted derivative, N4P4(NHR)8. X-ray crystal structure determinations of N3P3Cl2(NHC6H11) 4 (1a) and N4P4(NHC3H5)8 (2c) have been carried out. 1a crystallizes in a triclinic space group, P1, with a = 11.2330(13) Å, b = 11.4269(16) Å, c = 13.4055(12) Å, α = 72.211(10)°, β= 72.150(9)°, γ = 81.777(11)°, V = 1557.3(3) A°3, and Z = 2. 2c crystallizes in a monclinic space group, P21/n, with a = 12.433(3) Å, b = 20.484(4) Å, c = 12.645(3) Å, β = 92.81(2)°, V = 1557.3(3) A°3, and Z = 4. The cycloalkylamino-substituted polyphosphazenes contain a small amount of residual chlorine atoms. These have high glass transition temperatures.

UR - https://www.scopus.com/pages/publications/0000189934

U2 - 10.1021/ic980520j

DO - 10.1021/ic980520j

M3 - Article

AN - SCOPUS:0000189934

SN - 0020-1669

VL - 37

SP - 6192

EP - 6198

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 24

ER -

Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene

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