(C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure

Rachid Essehli; Brahim El Bali; Mohammed Lachkar; Michael Dusek; Fejfarova Karla; Michael Bolte

doi:10.1007/s10870-006-9113-5

(C₂N₂H₁₀)₂Mg(HP ₂O₇)₂·2H₂O synthesis and crystal structure

Rachid Essehli, Brahim El Bali, Mohammed Lachkar, Michael Dusek, Fejfarova Karla, Michael Bolte

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

(C₂N₂H₁₀)₂Mg(HP ₂O₇)₂·2H₂O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing [MgO ₄(H₂O)₂] octahedra resulting in chains, which are linked via [HP₂O₇] units to form [Mg(HP ₂O₇)₂(H₂O)₂] ^4- layers. The Mg²⁺ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation.

Original language	English
Pages (from-to)	655-660
Number of pages	6
Journal	Journal of Chemical Crystallography
Volume	36
Issue number	10
DOIs	https://doi.org/10.1007/s10870-006-9113-5
State	Published - Oct 2006
Externally published	Yes

Keywords

Diphosphate
Layered structure
Magnesium

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10.1007/s10870-006-9113-5

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title = "(C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure",

abstract = "(C2N2H10)2Mg(HP 2O7)2·2H2O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing [MgO 4(H2O)2] octahedra resulting in chains, which are linked via [HP2O7] units to form [Mg(HP 2O7)2(H2O)2] 4- layers. The Mg2+ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation.",

keywords = "Diphosphate, Layered structure, Magnesium",

author = "Rachid Essehli and {El Bali}, Brahim and Mohammed Lachkar and Michael Dusek and Fejfarova Karla and Michael Bolte",

year = "2006",

month = oct,

doi = "10.1007/s10870-006-9113-5",

language = "English",

volume = "36",

pages = "655--660",

journal = "Journal of Chemical Crystallography",

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TY - JOUR

T1 - (C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure

AU - Essehli, Rachid

AU - El Bali, Brahim

AU - Lachkar, Mohammed

AU - Dusek, Michael

AU - Karla, Fejfarova

AU - Bolte, Michael

PY - 2006/10

Y1 - 2006/10

N2 - (C2N2H10)2Mg(HP 2O7)2·2H2O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing [MgO 4(H2O)2] octahedra resulting in chains, which are linked via [HP2O7] units to form [Mg(HP 2O7)2(H2O)2] 4- layers. The Mg2+ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation.

AB - (C2N2H10)2Mg(HP 2O7)2·2H2O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing [MgO 4(H2O)2] octahedra resulting in chains, which are linked via [HP2O7] units to form [Mg(HP 2O7)2(H2O)2] 4- layers. The Mg2+ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation.

KW - Diphosphate

KW - Layered structure

KW - Magnesium

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U2 - 10.1007/s10870-006-9113-5

DO - 10.1007/s10870-006-9113-5

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SN - 1074-1542

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EP - 660

JO - Journal of Chemical Crystallography

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ER -

(C₂N₂H₁₀)₂Mg(HP ₂O₇)₂·2H₂O synthesis and crystal structure

Abstract

Keywords

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