Crystalline copper phosphates: Synthesis and thermal stability

Carlos E. Bamberger; E. D. Specht; Lawrence M. Anovitz

doi:10.1111/j.1151-2916.1997.tb03241.x

Crystalline copper phosphates: Synthesis and thermal stability

Carlos E. Bamberger
, E. D. Specht
, Lawrence M. Anovitz

Geochemistry & Interfacial Science

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The syntheses of Cu(PO₃)₂, Cu₂P₂O₇, Cu₄P₂O₉, Cu₅P₂O₁₀, Cu₃(PO₄)₂, and Cu₂PO₄ were accomplished by several new solid-state routes. Attempts to synthesize CuPO₃ were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO₃)₂, Cu₂P₂O₇ and Cu₃(PO₄)₂ were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.

Original language	English
Pages (from-to)	3133-3138
Number of pages	6
Journal	Journal of the American Ceramic Society
Volume	80
Issue number	12
DOIs	https://doi.org/10.1111/j.1151-2916.1997.tb03241.x
State	Published - Dec 1997

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10.1111/j.1151-2916.1997.tb03241.x

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title = "Crystalline copper phosphates: Synthesis and thermal stability",

abstract = "The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid-state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.",

author = "Bamberger, \{Carlos E.\} and Specht, \{E. D.\} and Anovitz, \{Lawrence M.\}",

year = "1997",

month = dec,

doi = "10.1111/j.1151-2916.1997.tb03241.x",

language = "English",

volume = "80",

pages = "3133--3138",

journal = "Journal of the American Ceramic Society",

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T1 - Crystalline copper phosphates

T2 - Synthesis and thermal stability

AU - Bamberger, Carlos E.

AU - Specht, E. D.

AU - Anovitz, Lawrence M.

PY - 1997/12

Y1 - 1997/12

N2 - The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid-state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.

AB - The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid-state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.

UR - https://www.scopus.com/pages/publications/0031360816

U2 - 10.1111/j.1151-2916.1997.tb03241.x

DO - 10.1111/j.1151-2916.1997.tb03241.x

M3 - Article

AN - SCOPUS:0031360816

SN - 0002-7820

VL - 80

SP - 3133

EP - 3138

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

IS - 12

ER -

Crystalline copper phosphates: Synthesis and thermal stability

Abstract

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